The electrochemical behavior of electrodes with an active layer comprised of TiO2, IrO2, RuO2, and SnO2 is studied. The zero-current potentials are determined. Curves of the rates of chlorine and oxygen release at the anode versus the composition of the electrode are presented.
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Here and below, content by weight, %, unless otherwise stipulated
References
V. A. Brodskii, A. F. Gubin, A. V. Kolesnikov, and N. A. Makarov, “Electro-surface properties of metal oxides and hydroxides in water solutions,” Steklo Keram., No. 6, 39 – 43 (2015); V. A. Brodskii, A. F. Gubin, A. V. Kolesnikov, and N. A. Makarov, “Electro-surface properties of metal oxides and hydroxides in water solutions,” Glass Ceram., 72(5 – 6), 220 – 224 (2015).
N. N. Gavrilova, V. V. Nazarov, A. S. Sitnik, and V. A. Kolesnikov, “Production of catalytic ceramic membranes based on the system CeO2–ZrO2 by the sol-gel method,” Steklo Keram., No. 7, 11 – 15 (2015); N. N. Gavrilova, V. V. Nazarov, A. S. Sitnik, and V. A. Kolesnikov, “Production of catalytic ceramic membranes based on the system CeO2–ZrO2 by the sol-gel method,” Glass Ceram., 72(7 – 8), 238 – 241 (2015).
A. M. Gaidukova, V. A. Brodskii, and V. A. Kolesnikov, “Purification of aqueous solutions by removal of variable-valence metals using oxide ruthenium-titanium electrodes,” Zh. Prikl. Khim., 87(9), 1221 – 1226 (2014).
V. A. Kolesnikov, D. O. Lemeshev, O. V. Yarovaya, et al., “Corundum-based substrates for membrane processes,” Steklo Keram., No. 5, 39 – 42 (2015); V. A. Kolesnikov, D. O. Lemeshev, O. V. Yarovaya, et al., “Corundum-based substrates for membrane processes,” Glass Ceram., 72(5 – 6), 180 – 183 (2015).
S. Cherevko and S. Geiger, “Oxygen and hydrogen evolution reactions on Ru, RuO2, Ir, and IrO2 thin film electrodes in acidic and alkaline electrolytes: A comparative study on activity and stability,” Catalysis Today, 262, 170 – 180 (2016).
P. Simon and Y. Gogotsi, “Materials for electrochemical capacitors,” Nature Mater., No. 7(11), 845 – 854 (2008).
T. X. Cai, H. Chen, H. Ju, and L. N. Lu, “Titanium anode with active coatings for cathodic protection of reinforced concrete structures,” Corros. Protect., 27, 522 – 525 (2006).
Y. Chen and D. Tang, “Studying on the titanium anodes coating with chlorine evolution and oxygen evolution syncretism,” Rare Metal Mater. Eng., 38, 1214 – 1218 (2009).
F. Liu, L. Ma, X. B. Li, and Y. G. Yan, “Study on the degradation of dye solution using Ti/IrO2–RuO2 electrode,” in: Water Resources and Environment. Proc. of the Intern. Conf. on Water Resources and Environment (2016), pp. 119 – 123.
C. Zhang, D. Tang, and X. Hu, “Scalable synthesis and excellent catalytic effect of hydrangea-like RuO2 mesoporous materials for lithium-O2 batteries,” Energy Storage Mater., 2, 8 – 13 (2016).
O. V. Yarovaya, D. O. Lemeshev, U. L. Mostovaya, et al., “Production of flat ceramic membrane contactors with a catalytically active layer based on Co3O4 ,” Steklo Keram., No. 1, 20 – 23 (2016); O. V. Yarovaya, D. O. Lemeshev, U. L. Mostovaya, et al., “Production of flat ceramic membrane contactors with a catalytically active layer based on Co3O4,” Glass Ceram., 73(1 – 2), 19 – 21 (2016).
X. Xuwen, C. Zhen, and L. Fuping, “Advanced treatment of biologically pretreated coking waste water by electrochemical oxidation using Ti/RuO2–IrO2 electrodes,” Chem. Technol. Biotechnol., No. 8, 1568 – 1575 (2013).
P. C. Deng, G.Wang, J. Z. Hu, and Y.W. Tian, “Electrochemical depolymerization of chitosans using the IrO2 electrode with interlayers as anode,” Mater. Sci. Forum, 847, 281 – 286 (2016).
C. Hernandez-Mejia, E. S. Gnanakumar, A. Olivos-Suarez, and J. Gascon, “Ru/TiO2-catalysed hydrogenation of xylose: The role of the crystal structure of the support,” Catalysis Sci. Technol., 6, 577 – 582 (2016).
T. É. S. Santos, R. S. Silva, K. I. B. Eguiluz, and G. R. Salazar-Banda, “Development of Ti/(RuO2)0.8(MO2)0.2 (M = Ce, Sn or Ir) anodes for atrazine electro-oxidation. Influence of the synthesis method,” Mater. Lett., 146, 4 – 8 (2015).
K. Kawaguchi and M. Morimitsu, “Effects of oxide composition on structure, surface morphology, and oxygen evolution behaviors of IrO2–Ta2O5 /Ti anodes prepared at a high temperature,” Electrochemistry, 83, 256 – 261 (2015).
V. G. Sevast’yanov, V. A. Kolesnikov, A. V. Desyatov, and A. V. Kolesnikov, “Conducting coatings based on carbon nanomaterials and SnO2 on glass for photoconverters,” Glass Ceram., 71(11 – 12), 421 – 424 (2014).
G. A. Kokarev, V. A. Kolesnikov, and Yu. I. Kapustin, Interphase Phenomena at an Oxide/Electrolytic Solution Interface [in Russian], RKkTU im. D. I. Mendeleeva, Moscow (2004).
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Translated from Steklo i Keramika, No. 12, pp. 23 – 28, December, 2016.
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Kolesnikov, V.A., Kapustin, Y.I., Isaev, M.K. et al. Metal Oxides: Promising Materials for Electrochemical Processes. Glass Ceram 73, 454–458 (2017). https://doi.org/10.1007/s10717-017-9910-7
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DOI: https://doi.org/10.1007/s10717-017-9910-7