The mechanism for the formation of chemically-heterogeneous polyethylene terephthalate (PETP) under industrial manufacturing conditions from dimethyl terephthalate and ethylene glycol was discussed in light of the results of a study of this polymer and the derived polymer gel. The chemical heterogeneity of PETP is attributed to side-reactions leading to the formation of relatively small bent macromolecules with short side-chains branchings.
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References
E. M. Aiznshtein, Tekst. Promyshl., No. 4, 28-34 (2009).
V. V. Korshak, Vysokomolek. Soedin., 15(A), No. 2, 298-309 (1973).
N. Grass, The Chemistry of Polymer Degradation [Russian translation), Izdatinlit, Moscow (1959).
B. V. Petukhov, Polyester Fibres [in Russian], Khimiya, Moscow (1976).
D. L. Nealy and L. J. Adams, J. Polymer Sci., A-1, 9, 2063-2070 (1971).
I. Kentazo, T. Akio, et al., J. Appl. Polymer Sci., 14, 2357-2376 (1970).
P. R. Cpanninger, J. Polymer Sci., 12, 709-717 (1974).
L. H. Buxbaum, ACS Polymer Prep., 8, 552 (1967).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 1 (16), 83-89 (2006).
N. A. Borshch, N. G. Mal’tseva, and I. V. Ivanova, Plast. Massy, No. 7, 47-49 (1984).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 1 (12), 103-106 (2004).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 2 (13), 48-52 (2004).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 1 (14), 62-64 (2005).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 1 (14), 53-56 (2005).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 2 (17), 78-83 (2006).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 1 (18), 26-30 (2007).
N. A. Borshch, Izv. Kursk. Gos. Tekhn. Univ., No. 1, 25-30 (2008).
N. A. Borshch, Izv. Yugo-Zapadn. Gos. Univ., Ser. Fizika i Khimiya, No. 1, 41-49 (2014).
D. Kennedy, Vysokomol. Soedin., Ser. A, 25, No. 7, 1560 (1985).
E. Ceausescu, New Studies on High-Molecular-Weight Compounds [Russian translation], Khimiya, Moscow (1983).
N. A. Borshch, N. G. Mal’tseva, and G. Yu. Salai, Zh. Analit. Khim., 39, No. 9, 1603-1605 (1984).
L. Mandel’kern, Crystallization of Polymers [in Russian], Nauka, Moscow-Leningrad (1966).
N. A. Borshch and N. G. Mal’tseva, Zh. Analit. Khim., 41, No. 5, 916-922 (1986).
H. Becker, Introduction to the Electronic Theory of Organic Reactions [Russian translation], Mir, Moscow (1977), p. 415.
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Translated from Khimicheskie Volokna, Vol. 49, No. 2, pp. 3-11, March-April, 2017.
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Borshch, N.A. The Mechanism of the Formation of Chemically-Heterogeneous Polyethylene Terephthalate during its Industrial Manufacture from Dimethyl Terephthalate and Ethylene Glycol . Fibre Chem 49, 79–87 (2017). https://doi.org/10.1007/s10692-017-9848-0
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DOI: https://doi.org/10.1007/s10692-017-9848-0