Abstract
This study was performed to characterize hydrochemical properties of springs based on their geological origins in Taiwan. Stepwise discriminant analysis (DA) was used to establish a linear classification model of springs using hydrochemical parameters. Two hydrochemical datasets—ion concentrations and relative proportions of equivalents per liter of major ions—were included to perform prediction of the geological origins of springs. Analyzed results reveal that DA using relative proportions of equivalents per liter of major ions yields a 95.6% right assignation, which is superior to DA using ion concentrations. This result indicates that relative proportions of equivalents of major hydrochemical parameters in spring water are more highly associated with the geological origins than ion concentrations do. Low percentages of Na + equivalents are common properties of springs emerging from acid-sulfate and neutral-sulfate igneous rock. Springs emerging from metamorphic rock show low percentages of Cl − equivalents and high percentages of HCO\(_{3}^{-}\) equivalents, and springs emerging from sedimentary rock exhibit high Cl − /SO\(_{4}^{2-}\) ratios.
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References
Afşin, M., Kuşcu, I., Elhatip, H., & Dirik, K. (2006). Hydrogeochemical properties of CO2-rich thermal-mineral waters in Kayseri (Central Anatolia), Turkey. Environmental Geology, 50, 24–36.
Alberto, W. D., Pilar, D. M., Valeria, A. M., Fabiana, P. S., Cecilia, H. A., & Los Angeles, B. M. (2001). Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality. A case study: Suquia riverbasin (Córdoba, Argentina). Water Research, 35, 2881–2894.
Alfaro, C., & Wallace, M. (1994). Origin and classification of springs and historical review with current applications. Environmental Geology, 24, 112–124.
APHA (1998). Standard methods for the examination of water and water waste (20th ed., pp. 4–158). Washington: American Public Health Assoc.
Chen, W. F., & Sung, M. (2009). The redox potential of hot springs in Taiwan. Terrestrial, Atmospheric and Oceanic Sciences, 20(3), 465–479.
Chen, Y. L. (2002). Chemical compositions of hot spring waters in the Tatun volcanic area and their influence on stream waters (pp. 176–197.). Ph.D. Dissertation, Institute of Geosciences, National Taiwan University, Taipei.
Cheng, W. T. (1985). Geothermal update report: Taiwan, Republic of China. In Geothermal Resources Council 9, 1985 international symposium on geothermal energy (pp. 191–195). CA, USA.
Cherng, F. P., & Wang, J. R. (1984). Corrosion of metals by geothermal fluids in Taiwan’s Tatun volcanic region and novel approaches for controlling the problem. In Proceedings of the international symposium on solving corrosion and scaling problems in geothermal systems (pp. 285–293). San Francisco, CA, USA.
Cruz, J. V., & França, Z. (2006). Hydrogeochemistry of thermal and mineral water springs of the Azores archipelago (Portugal). Journal of Volcanology and Geothermal Research, 151, 382–398.
Davisson, M. L., Avisson, M. L., Presser, T. S., & Criss, R. E. (1994). Geochemistry of tectonically expelled fluids from the northern coast ranges, Rumsey-Hills, California, USA. Geochimica et Cosmochimica Acta, 58, 1687–1699.
Delmelle, P., Bernard, A., Kusakabe, M., Fischer, T. P., & Takano, B. (2000). Geochemistry of the magmatic-hydrothermal system of Kawah Ijen volcano, East Java, Indonesia. Journal of Volcanology and Geothermal Research, 97, 31–53.
Freeze, R. A., & Cherry, J. A. (1979). Groundwater (pp. 413–416). New Jersey: Prentice Hall.
González-Partida, E., Carrillo-Chávez, A., Levresse, G., Tello-Hinojosa, E., Venegas-Salgado, S., Ramirez-Silva, G., et al. (2005). Hydro-geochemical and isotopic fluid evolution of the Los Azufres geothermal field, Central Mexico. Applied Geochemistry, 20, 23–39.
Ho, C. S. (1988). An introduction to the geology of Taiwan, explanatory text of the geologic map of Taiwan. Central Geological Survey, the Ministry of Economic Affairs, Taipei, Taiwan.
Hsu, B. M., Chen, C. H., Wan, M. T., & Cheng, H. W. (2006). Legionella prevalence in hot spring recreation areas of Taiwan. Water Research, 40, 3267–3273.
ITRI (Industrial Technology Research Institute) (2004). A study on the investigation, exploitation and utilization of hot-spring resources in Taiwan (1/4–4/4) (49 pp.). Water Resources Agency (MOEA/WRA-920036V4), Taipei.
Kreamer, D. K., Hodge, V. F., Rabinowitz, I., Johannesson, K. H., & Stetzenbach, K. J. (1996). Trace element geochemistry in water from selected springs in Death Valley National Park, California. Ground Water, 34, 95–103.
Lambrakis, N., Antonakos, A., & Panagopoulos, G. (2004). The use of multicomponent statistical analysis in hydrogeological environmental research. Water Research, 38, 1862–1872.
Lee, H. F., Yang, T. F., Lan, T. F., Song, S. R., & Tsao, S. (2005). Fumarolic gas composition of the Tatun Volcano Group, Northern Taiwan. Terrestrial, Atmospheric and Oceanic Sciences, 16, 843–863.
Lee, J. J., Jang, C. S., Wang, S. W., Liang, C. P., & Liu, C. W. (2008). Delineation of spatial redox zones using discriminant analysis and geochemical modeling in arsenic-affected groundwater aquifers. Hydrological Processes, 22, 3029–3041.
Mariner, R. H., Evans, W. C., Presser, T. S., & White, L. D. (2003). Excess nitrogen in selected thermal and mineral springs of the Cascade Range in northern California, Oregon, and Washington: Sedimentary or volcanic in origin? Journal of Volcanology and Geothermal Research, 121, 99–114.
Meinzer, O. E. (1927). Large springs in the United States (94 pp.). U.S. Geological Survey, Water Supply Paper 557.
Minissale, A., Magro, G., Vaselli, O., Verrucchi, C., & Perticone, I. (1997). Geochemistry of water and gas discharges from the Mt. Amiata silicic complex and surrounding areas (central Italy). Journal of Volcanology and Geothermal Research, 79, 223–251.
Papatheodorou, G., Demopoulou, G., & Lambrakis, N. (2006). A long-term study of temporal hydrochemical data in a shallow lake using multivariate statistical techniques. Ecological Modelling, 193, 759–776.
Papatheodorou, G., Lambrakis, N., & Panagopoulos, G. (2007). Application of multivariate statistical procedures to the hydrochemical study of a coastal aquifer: An example from Crete, Greece. Hydrological Processes, 21, 1482–1495.
Samsudin, A. R., Hamzah, U., Rahman, R. A., Siwar, C., Jani, M. F. M., & Othman, R. (1997). Thermal springs of Malaysia and their potential development. Journal of Asian Earth Sciences, 15, 275–284.
Sanada, T., Takamatsu, N., & Yoshiike, Y. (2006). Geochemical interpretation of long-term variations in rare earth element concentrations in acidic hot spring waters from the Tamagawa geothermal area, Japan. Geothermics, 35, 141–155.
Sawyer, C. N., & McCarty, P. L. (1978). Chemistry for environmental engineering (3rd ed., pp. 371–373). New York: McGraw-Hill.
Sharma, S. (1996). Applied multivariate techniques (pp. 264–273). New York: Wiley.
Song, S. R., Chen, Y. L., Kiu, C. M., Ku, W. Y., Chen, H. F., Liu, Y. J., et al. (2005). Hydrochemical changes in spring waters in Taiwan: Implications for evaluating sites for earthquake precursory monitoring. Terrestrial, Atmospheric and Oceanic Sciences, 16, 745–762.
SPSS Inc. (1998). SPSS BASE 8.0-Application Guide. SPSS Inc., Chicago.
Stambuk-Gilijanovic, N. (2008). Characteristics and origin of the hydrogen sulphide spring water from Split spa (Southern Croatia). Environmental Monitoring and Assessment, 140, 109–117.
Sukenik, S., Flusser, D., & Abu-Shakra, M. (1999). The role of spa therapy in various rheumatic diseases. Rheumatic Disease Clinics of North America, 25, 883–897.
Swanson, S. K., Bahr, J. M., Schwar, M. T., & Potter, K. W. (2001). Two-way cluster analysis of geochemical data to constrain spring source waters. Chemical Geology, 179, 73–91.
Tarits, C., Renaut, R. W., Tiercelin, J. J., Hérissé, A. L., Cotton, J., & Cabon, J. Y. (2006). Geochemical evidence of hydrothermal recharge in Lake Baringo, central Kenya Rift Valley. Hydrological Processes, 20, 2027–2055.
Wiggine, B. A., Andrew, R. W., Conway, R. A., Corr, C. L., Dobratz, E. J., Dougherty, D. P., et al. (1999). Use of antibiotic resistance analysis to identify nonpoint sources of fecal pollution. Applied Environmental Microbiology, 65, 3483–3486.
WRA (Water Resources Agency) (2003). Law of Hot Springs. Water Resources Agency, Ministry of Economic Affair, Taiwan (Available at http://www.wra.gov.tw).
Yee, N., Phoenix, V. R., Konhauser, K. O., Benning, L. G., & Ferris, F. G. (2003). The effect of cyanobacteria on silica precipitation at neutral pH: Implications for bacterial silicification in geothermal hot springs. Chemical Geology, 199, 83–90.
Zhu, B. Q., & Yu, H. (1995). The use of geochemical indicator elements in the exploration for hot water sources within geothermal fields. Journal of Geochemical Exploration, 55, 125–136.
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Jang, CS., Chen, JS., Lin, YB. et al. Characterizing hydrochemical properties of springs in Taiwan based on their geological origins. Environ Monit Assess 184, 63–75 (2012). https://doi.org/10.1007/s10661-011-1947-4
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DOI: https://doi.org/10.1007/s10661-011-1947-4