It was found that the reaction of 2-hydroxy-5,7,8-trimethyl-2H-1,2-benzoxaphosphinine 2-oxide with resorcinol and its derivatives as well as sesamol leads to the formation of phosphaneoflavanones in high yields. The obtained phosphaneoflavanones are precursors in the synthesis of novel unsymmetrical cage phosphonates. The structures of the obtained products were confirmed by IR spectroscopy, 1H, 13C NMR spectroscopy, and X-ray structural analysis.
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The study was carried out with the financial support of the Russian Foundation for Basic Research within the framework of the scientific project 20-03-00118.
The authors are grateful to the Collective Spectro-Analytical Center for Physicochemical Studies of the Structure, Properties and Composition of Substances and Materials of Kazan Scientific Center, Russian Academy of Sciences for technical support of the studies. X-ray structural analysis was performed using the equipment of the Center for Collective Use of Physical Methods for the Study of Substances and Materials of Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, which functions with the support of the State Assignment to Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental scientific research
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(11), 1605–1610
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Sadykova, Y.M., Zalaltdinova, A.V., Smailov, A.K. et al. Synthesis of unsymmetrical cage phosphonates from heterocyclic systems based on 2H-1,2-benzoxaphosphinine. Chem Heterocycl Comp 56, 1605–1610 (2020). https://doi.org/10.1007/s10593-020-02856-5
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DOI: https://doi.org/10.1007/s10593-020-02856-5