Abstract
In the phase diagram of carbon, the positions of the melting and thermodynamic-equilibrium curves of detonation nanodiamonds or ultrafine diamonds are found as functions of diamond particle size. The position of the set of triple points located in the ranges of pressure 13.5–16.5 GPa and temperature 2210–4470 K and determining the region of the liquid state of nanocarbon is determined. In the phase diagram of nanocarbon, the diamond region is divided into three parts according to the type of nanoparticles: nanodiamond, liquid nanocarbon (nanodrops), and amorphous nanocarbon.
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REFERENCES
K. V. Volkov, V. V. Danilenko, and V. V. Elin, “Synthesis of diamond from the carbon of the explosive detonation products,” Fiz. Goreniya Vzryva, 26, No.3, 123–125 (1990).
V. V. Danilenko, Synthesis and Sintering of Diamond by Detonation [in Russian], Energoatomizdat, Moscow (2003).
I. D. Morokhov, L. I. Trusov, and S. P. Chizhik, Ultrafine Metallic Media [in Russian], Atomizdat, Moscow (1977).
Yu. I. Petrov, Physics of Fine Particles [in Russian], Nauka, Moscow (1982).
I. D. Morokhov, L. I. Trusov, and V. N. Lapovok, Physical Phenomena in Disperse Phases [in Russian], Energoatomizdat, Moscow (1984).
Chen Quan, Yun Sou Rong, Huang Feng, Lei Ding Jing, “Study of formation of condensed carbon in detonation by analyzing graphite and diamond crystallites in soot,” in: 11th Int. Detonation Symp., Snowmass, Colorado, USA, Aug. 29–Sept. 4 (1998), pp. 214–215.
S. A. Gubin, V. V. Odintsov, V. I. Pepekin, and S. S. Sergeev, “Effect of the shape and size of graphite and diamond crystals on the phase equilibrium of carbon and HE detonation parameters,” Khim. Fiz., 9, No.3, 401–417 (1990).
S. A. Gubin, V. V. Odintsov, V. I. Pepekin, and S. S. Sergeev, “Effect of the shape and size of graphite and diamond crystals on the phase equilibrium of carbon and HE detonation parameters,” in: IV All-Union Conf. on Detonation, Vol. 1 (1988), pp. 13–19.
M. van Thiel and F. H. Ree, “Properties of carbon clusters in TNT detonation products. Graphite-diamond transition,” J. Appl. Phys., 62, No.5, 1761–1767 (1987).
S. B. Viktorov, S. A. Gubin, I. V. Maklashova, “Thermodynamic calculation of the phase diagram of ultrafine carbon,” in: Physical Chemistry of Disperse Systems, Proc. IV All-Union Conf., Moscow Physicotechnical Institute, Moscow (1999), pp. 195–196.
S. B. Viktorov, S. A. Gubin, I. V. Maklashova, “Equations of state of ultrafine particles of graphite and diamond,” in: Physical Chemistry of Disperse Systems, Proc. V All-Union Conf., Moscow Physicotechnical Institute, Moscow (2000), pp. 49–50.
S. V. Razorenov, G. I. Kanel’, and A. A. Ovchinnikov, “Recording shock waves by Manganin sensors and graphite-diamond transition pressures at elevated temperatures,” in: Detonation, Proc. II All-Union Conf. on Detonation, Chernogolovka, Issue 2 (1981), pp. 70–72.
A. E. Aleksenskii, M. V. Baidakova, A. Ya. Vul’, and V. I. Siklitskii, “Structure of diamond clusters, ” Fiz. Tverd. Tela, 41, No.4, 740–743 (1999).
A. E. Aleksenskii, M. V. Baidakova, A. Ya. Vul’, et al., “Diamond-graphite phase transition in ultrafine diamond clusters,” Fiz. Tverd. Tela, 39, No.6, 1125–1134 (1997).
I. Yu. Malkov and V. M. Titov, “Structure and properties of detonation soot particles,” in: Shock Compression of Condensed Matter 1995: Proc. of the Conf. of the American Physical Society Topical Group on Shock Compression of Condensed Matter (Seattle, USA, August 13–18, 1995), AIR Press, Part 2 (1995), pp. 783–786.
A. L. Vereshchagin, “Phase diagram of ultrafine carbon,” Combust., Expl., Shock Waves, 38, No.3, 358–359 (2002).
V. F. Anisichkin and I. Yu. Mal’kov, “Thermodynamic stability of ultradispersed diamond phase,” Combust., Expl., Shock Waves, 24, No.5, 631–633 (1988).
P. Badziag, W. S. Verwoerd, W. P. Ellis, and N. R. Greiner, “Nanometer-sized diamonds are more stable than graphite,” Nature, 343, 244–245 (1990).
V. V. Danilenko, “Thermodynamics of graphite to diamond transformation,” Combust., Expl., Shock Waves, 24, No.5, 633–637 (1988).
S. N. Zadumkin, “On the value of the interfacial surface energy of metals on the crystal-melt interface, ” Dokl. Akad. Nauk SSSR, 130, 4 (1960).
D. F. Fedoseev, N. V. Niovikov, and A. S. Vishnevskii (eds.), Diamond: Handbook [in Russian], Naukova Dumka, Kiev (1981).
M. Togaya, “Thermophysical properties of carbon at high pressure,” in: Advanced Materials’96: Proc. of the 3rd NIRIM Int. Symp. on Advanced Materials (ISAM’96), Tsukuba, Jpn., March 4–8 (1996), pp. 251–256.
A. M. Molodets, “Free energy of diamond,” Combust., Expl., Shock Waves, 34, No.4, 453–460 (1998).
V. N. Korobenko and A. I. Savvatimskiy, “Blackbody design for high temperature (1800 to 5500 K) of metals and carbon in liquid states under fast heating,” in: Temperature: Its Measurement and Control in Science and Industry, Vol. 7, New York (2003), pp. 783–788.
V. M. Titov, V. F. Anisichkin, and I. Yu. Mal’kov, “Synthesis of ultradispersed diamond in detonation waves,” Combust., Expl., Shock Waves, 25, No.3, 372–379 (1989).
S. B. Kormer, M. V. Sinitsyn, G. A. Kirillov, and V. D. Urlin, “Experimental determination of the temperatures of shock-compressed NaCl and KCl and their melting curves up to pressures of 700 kbar,” Zh. Eksp. Teor. Fiz., 48, 1033 (1965).
Huang Fenglei, Tong Yi, and Yun Shourong, “Synthesis mechanism and technology of ultrafine diamond from detonation,” Fiz. Tverd. Tela, 46, No.4, 601–604 (2004).
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Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 4, pp. 110–116, July–August, 2005.
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Danilenko, V.V. Phase Diagram of Nanocarbon. Combust Explos Shock Waves 41, 460–466 (2005). https://doi.org/10.1007/s10573-005-0056-5
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DOI: https://doi.org/10.1007/s10573-005-0056-5