Abstract
A new carbon nanofibrous mat with necklace-like structures have been prepared by carbonization of cellulose/carbon black (CB) nanofibers through electrospinning of cellulose acetate/CB blend solution followed by deacetylation. The effect of carbon black on the thermal stability of the precursor and morphology of the CNFs were investigated using thermogravimetric analysis, field emission scanning electron microscopy (FE-SEM) and Raman spectroscopy. The FE-SEM images showed that cellulose derived CNFs form matrix for accomplishing necklace-like fibers containing spherical CB nanoparticles with diameter between 30 and 60 nm after heating of cellulose/CB nanofibers. It is demonstrated that the incorporation of CB particles increases the electrical conductivity from 1.4 to 16 mS and carbon yield from 12 to 30%. Carbon nanofibers based on cellulose/CB was evaluated as a suitable adsorbent for removal of methylene blue (MB) from water. The final dye removal was found to be 97% at the initial MB concentration of 20 mg L−1. This study suggests a new carbon nanofiber structure that will be potentially useful for energy applications and water treatment.
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Bansal RC (2005) Activated carbon adsorption. CRC Press, Boca Raton
Brennan LJ, Byrne MT, Bari M, Gun YK (2011) Carbon nanomaterials for dye-sensitized solar cell applications: a bright future. Adv Energy Mater 1:472–485
Chae HG, Choi YH, Minus ML, Kumar S (2009) Carbon nanotube reinforced small diameter polyacrylonitrile based carbon fiber. Compos Sci Technol 69:406–413
Chand S (2000) Carbon fibers for composites. J Mater Sci 35:1303–1313
Deng L, Young RJ, Kinloch IA, Abdelkader AM, Holmes SM, De Haro-Del R, David A, Eichhorn SJ (2013a) Supercapacitance from cellulose and carbon nanotube nanocomposite fibers. ACS Appl Mater Interfaces 5:9983–9990
Deng L, Young RJ, Kinloch IA, Zhu Y, Eichhorn SJ (2013b) Carbon nanofibres produced from electrospun cellulose nanofibres. Carbon 58:66–75
Dumanli AG, Windle AH (2012) Carbon fibres from cellulosic precursors: a review. J Mater Sci 47:4236–4250
Ekrami E, Dadashian F, Soleimani M (2014) Waste cotton fibers based activated carbon: optimization of process and product characterization. Fibers Polym 15:1855–1864
Frank E, Hermanutz F, Buchmeiser MR (2012) Carbon fibers: precursors, manufacturing, and properties. Macromol Mater Eng 297:493–501
Frey MW (2008) Electrospinning cellulose and cellulose derivatives. Polym Rev 48:378–391
Gaminian H, Montazer M (2017) Decorating silver nanoparticles on electrospun cellulose nanofibers through a facile method by dopamine and ultraviolet irradiation. Cellulose 24:3179–3190
Guo Q, Zhou X, Li X, Chen S, Seema A (2009) Supercapacitors based on hybrid carbon nanofibers containing multiwalled carbon nanotubes. J Mater Chem 19:2810–2816
Gupta VK (2009) Application of low-cost adsorbents for dye removal—a review. J Environ Manage 90:2313–2342
Hwang J, Muth J, Ghosh T (2006) Electrical and mechanical properties of carbon-black-filled, electrospun nanocomposite fiber webs. J Appl Polym Sci 104:2410–2417
Jawhari T, Roid A, Casado J (1995) Raman spectroscopic characterization of some commerically available carbon black material. Carbon 33:1561–1565
Jazaeri E, Zhang L, Wang X, Tsuzuki T (2011) Fabrication of carbon nanofiber by pyrolysis of freeze-dried cellulose nanofiber. Cellulose 18:1481–1485
Kilzer FJ, Broido A (1965) Speculations on the nature of cellulose pyrolysis. Pyrodynamics 2:151–163
Kuzmenko V, Naboka O, Gatenholm P, Enoksson P (2014) Ammonium chloride promoted synthesis of carbon nanofibers from electrospun cellulose acetate. Carbon N Y 67:694–703
Kuzmenko V, Naboka O, Haque N, Staaf H, Goransson G, Gatenholm P, Peter Enoksson P (2015) Capacitive effects of nitrogen doping on cellulose-derived carbon nanofibers. Mater Chem Phys 160:59–65
Lau AC, Furlong DN, Healy TW, Grieser F (1986) The electrokinetic properties of carbon black and graphitized carbon black aqueous colloids. Colloids Surf 18:93–104
Liu Y, Qin W, Wang Q, Liu R, Liu H (2015) Glassy carbon nanofibers from electrospun cellulose nanofiber. J Mater Sci 50:563–569
Park SJ (2014) Carbon fibers. Springer, Berlin
Patil SA, Chigome S, Hägerhäll C, Torto N, Gorton L (2013) Bioresource technology electrospun carbon nanofibers from polyacrylonitrile blended with activated or graphitized carbonaceous materials for improving anodic bioelectrocatalysis. Bioresour Technol 132:121–126
Peter KT, Vargo JD, Rupasinghe TP, De Jesus A, Tivanski AV, Sander EA, Myung NV, Cwiertny DM (2016) Synthesis, optimization, and performance demonstration of electrospun carbon nanofiber–carbon nanotube composite sorbents for point-of-use water treatment. ACS Appl Mater Interfaces 8:11431–11440
Rodriguez K, Gatenholm P, Renneckar S (2012) Electrospinning cellulosic nanofibers for biomedical applications: structure and in vitro biocompatibility. Cellulose 19:1583–1598
Soares BG, Calheiros LF, Barra GMO (2016) Effect of double percolation on the electrical properties and electromagnetic interference shielding effectiveness of carbon-black- loaded polystyrene/ethylene vinyl acetate copolymer blends. J Appl Polym Sci 133:1–10
Sumita M, Sakata K, Asai S, Miyasaka K, Nakagawa H (1991) Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black. Polym Bull 25:265–271
Sun J, Chang S, Lee S, Lee Y (2010) Improved gas sensing of electrospun carbon fibers based on pore structure, conductivity and surface modification. Carbon 48:2573–2581
Suzuki M (1994) Activated carbon fiber: fundamentals and applications. Carbon 32:577–586
Tai Z, Yan X, Lang J, Xue Q (2012) Enhancement of capacitance performance of flexible carbon nanofiber paper by adding graphene nanosheets. J Power Sources 199:373–378
Tarasova E, Byzova A, Savest N, Viirsalu M, Gudkova V, Märtson T, Krumme A (2014) Influence of preparation process on morphology and conductivity of carbon black-based electrospun nanofibers. Fuller Nanotub Carbon Nanostruct 23:695–700
Tungprapa S, Puangparn T, Weerasombut M, Jangchud I, Fakum P, Semongkhol S, Meechaisue C, Supaphol P (2007) Electrospun cellulose acetate fibers: effect of solvent system on morphology and fiber diameter. Cellulose 14:563–575
Xie H, Yang Q, Sun X, Yang J, Huang Y (2006) Gas sensor arrays based on polymer-carbon black to detect organic vapors at low concentration. Sens Actuators B Chem 113:887–891
Yu Y, Gu L, Wang C, Dhanabalan A, Aken PV, Maier J (2009) Encapsulation of Sn@ carbon nanoparticles in bamboo-like hollow carbon nanofibers as an anode material in lithium-based batteries. Angew Chem Int Ed 48:6485–6489
Zhu L, Lu Y, Wang Y, Zhang L, Wang W (2012) Preparation and characterization of dopamine-decorated hydrophilic carbon black. Appl Surf Sci 258:5387–5393
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Gaminian, H., Montazer, M. Carbon black enhanced conductivity, carbon yield and dye adsorption of sustainable cellulose derived carbon nanofibers. Cellulose 25, 5227–5240 (2018). https://doi.org/10.1007/s10570-018-1929-6
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DOI: https://doi.org/10.1007/s10570-018-1929-6