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Chiral Polymer-Mediated Pd@MOF-808 for Efficient Sequential Asymmetric Reaction

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Abstract

The design and construction of organocatalysts that combined the homogeneous and heterogeneous natures to realize efficient catalysis are highly desired and challenging. Functionalized-polymers, a kind of flexible materials, provide a platform to modulate the states of immobilized catalysts in rigid supports. Herein, a chiral polymer (CP) mediated catalyst containing Pd NPs have been reported (CP@Pd@MOF-808). Chiral active sites were anchored on the polymer, and the chiral polymer threaded within the host pores of MOFs to promise the homogeneousness of chiral sites in a heterogeneous support MOF-808. This strategy kept the flexibility and freedom of chiral sites after immobilization, thus exhibited comparable performances with the corresponding homogeneous catalyst. The well-designed CP@Pd@MOF-808 was applied to sequential asymmetric reactions with excellent reactivity and stereoselectivity (up to 89% yields and 95% ee values), which were even better than that of homogeneous catalyst.

Graphical Abstract

A rationally designed Chiral Polymer-Mediated MOF catalyst containing metal NPs was developed for sequential reaction with high efficiency.

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Acknowledgements

We are grateful for financial support from the Natural Science Foundation of Jiangsu Province (BK20131289), the Fundamental Research Funds for the Central Universities, the National Natural Science Foundation of China (No. 21471031) and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Yi-Ming Li, Liumei Cao, Hao Ren, Chun-Yan Ji, Wenjing Li & Lin Cheng

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  1. Yi-Ming Li
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Li, YM., Cao, L., Ren, H. et al. Chiral Polymer-Mediated Pd@MOF-808 for Efficient Sequential Asymmetric Reaction. Catal Lett 153, 1193–1204 (2023). https://doi.org/10.1007/s10562-022-04053-9

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