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Pd(II)-Metalated and l-Proline-Decorated Multivariate UiO-67 as Bifunctional Catalyst for Asymmetric Sequential Reactions

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Abstract

The construction of a multifunctional catalyst for multistep sequential\tandem reactions at the molecular level faces a formidable challenge. Multivariate (MTV)-MOFs can provide a facile and tunable platform for rationally designing such multifunctional catalysts via grafting different catalytic groups on the bridging ligands. However, the related investigations are still limited. Here, Pd(II) and l-proline are metalated and decorated to organic linkers, respectively, to build a MTV-MOF, which is then successfully applied to sequential Suzuki Coupling/asymmetric Aldol reactions with satisfied coupling performance (yields up to 99%) and good enantioselectivities (eeanti up to 98%). Inductively coupled plasma optical emission spectrometer (ICP-OES) measurements of the supernatant and hot leaching test suggest the heterogeneous nature of the catalyst. Macrosubstrate tests verify that the reaction occurs inside the pores of the MOF. The heterogeneous catalyst can maintain structural stability and catalytic activity within three cycles.

Graphic Abstract

Versatile Pd(II) and l-proline were metalated and decorated, respectively, into stable UiO-67 to construct bifunctional and heterogeneous multivariate MOF catalyst, which displayed efficient and recyclable catalytic activity in sequential Suzuki Coupling/asymmetric Aldol reactions.

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Acknowledgements

This work was supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions, National Natural Science Foundation of China (No. 21471031) and Fundamental Research Funds for the Central Universities.

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  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 210009, People’s Republic of China

    Lin Cheng, Liumei Cao, Hao Ren, Qiaoqiao Guo, Huifang Deng & Yiming Li

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  2. Liumei Cao
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Cheng, L., Cao, L., Ren, H. et al. Pd(II)-Metalated and l-Proline-Decorated Multivariate UiO-67 as Bifunctional Catalyst for Asymmetric Sequential Reactions. Catal Lett 152, 1160–1169 (2022). https://doi.org/10.1007/s10562-021-03719-0

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