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Kinetics Study of the Esterification Reaction of Cyclohexene to Cyclohexyl Acetate Catalyzed by Novel Brønsted–Lewis Acids Bifunctionalized Heteropolyacid Based Ionic Liquids Hybrid Solid Acid Catalysts

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Abstract

A series of Brønsted–Lewis acids bifunctionalized heteropolyacid based ionic liquids hybrid solid acid catalysts (BLA-HPA-ILs) were synthesized by combining the Brønsted acidic ionic liquid [Bis–Bs–BDMAEE]HPW12O40 with metallic oxide in different composition ratios and applied in the esterification of cyclohexene to cyclohexyl acetate. Among the synthesized catalysts, the 1/2Cu[Bis–Bs–BDMAEE]HPW12O40 catalyst with Brønsted and Lewis acidities shown the most excellent catalytic performance for the esterification of cyclohexene with acetic acid. The BLA-HPA-ILs catalysts were characterized by elemental analysis, FT-IR, Py-IR, TG, 1H NMR, SEM and EDX. The effects of reaction temperature, catalyst dosage, and initial reactant molar ratio has been investigated in detail. A pseudohomogeneous (PH) kinetic model was used to correlate the kinetic data in the temperature range of 333.15–363.15 K, and the kinetic parameters were estimated, indicating the results calculated by the kinetic model are well coincidence with the experimental results. Moreover, as a heterogeneous reaction catalyst, 1/2Cu[Bis–Bs–BDMAEE]HPW12O40 could be easily recovered by a simple treatment and reused six times without any obvious decrease in catalytic activity, displaying good reusability.

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Abbreviations

A :

Cyclohexene

B :

Acetic acid

D :

Cyclohexyl acetate

HPA:

Heteropolyacid

ILs:

Ionic liquids

HPA-ILs:

Heteropolyacid based ionic liquids hybrid

BLA-ILs:

Brønsted–Lewis acidic ILs

BLA-HPA-ILs:

Brønsted–Lewis acids bifunctionalized heteropolyacid based ionic liquids hybrid solid acid

[Bis–Bs–BDMAEE]:

[HO3S–(CH2)4–BDMAEE–(CH2)4–SO3H]

PH:

Pseudohomogeneous

K e :

Equilibrium constant

k + :

Forward reaction rate constant (mol−1 min−1)

k − :

Reverse reaction rate constant (mol−1 min−1)

k 0 :

Pre-exponential factor (L2 mol−2 min−1)

C i :

The molar concentration of component i (mol L−1)

m cat :

The catalyst dosage per unit volume (g L−1)

T :

Temperature (K)

t :

Time (min)

Δ r H 0 :

The reaction enthalpy (kJ mol−1)

Δ r S :

Entropy (J mol−1 K−1)

x :

Conversion of cyclohexene

x cal :

Calculated conversion

x exp :

Experimental conversion

E a :

Activation energy (kJ mol−1)

SRS :

Minimum sum of residual squares

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Acknowledgements

This work was supported by the National Natural Science Foundations of China (No. 21676072), Henan Science and Technology Research Project (212102210653, 202102310285), China Postdoctoral Science Foundation (2020M672209), and Scientific Research Projects for Higher Education of Henan Province (20A530002),  the Program for Innovation Teams in Science and Technology in Universities of Henan Province (20IRTSTHN004).

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Authors and Affiliations

  1. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, People’s Republic of China

    Binxiong Guang, Yuefeng Wu, Weihua Liu, Jianhong Wang, Yahui Xiao & Yong Liu

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  1. Binxiong Guang
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  2. Yuefeng Wu
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  3. Weihua Liu
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Correspondence to Jianhong Wang or Yong Liu.

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Guang, B., Wu, Y., Liu, W. et al. Kinetics Study of the Esterification Reaction of Cyclohexene to Cyclohexyl Acetate Catalyzed by Novel Brønsted–Lewis Acids Bifunctionalized Heteropolyacid Based Ionic Liquids Hybrid Solid Acid Catalysts. Catal Lett 152, 75–86 (2022). https://doi.org/10.1007/s10562-021-03626-4

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