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Distribution of Products from Catalytic Conversion of Cellulose Over Metal-Modified Hierarchical H-ZSM-5 in Aqueous Media

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Abstract

A series of metal-modified hierarchical M/H-ZSM-5 catalysts were prepared for catalytic conversion of cellulose in an aqueous medium. Characterization of the catalysts showed that the impregnation of metal into H-ZSM-5 did not change the basic framework and pore structure of H-ZSM-5, but it decreased the total acidity. Analysis of the products indicated that the catalysts significantly affected products distribution. When Co/H-ZSM-5 and Fe/H-ZSM-5 were used as the catalysts, the yields of lactic acid and cyclic ketones obviously increased. At last, a recommendable catalytic transformation pathway of cellulose over M/H-ZSM-5 was proposed on the basis of the obtained experimental results and the published literatures.

Graphical Abstract

In this paper, a series of metal-modified hierarchical M/H-ZSM-5 (M = Ce, Co, Ga, and Fe) catalysts were prepared and employed in catalytic conversion of cellulose in aqueous media to examined the products distribution of cellulose catalytic conversion. Based on our results and previous works, the plausible general reaction pathways of cellulose over M/H-ZSM-5 were proposed.

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Acknowledgements

This study was supported financially by “the Fundamental Research Funds for the Central Universities” (No. 17lgpy71), National Science for Distinguished Young Scholars of China (No. 21425627), the Natural Science Foundation of Guangdong Province (No. 2018A0303130062), and Science and Technology Innovation Teams Project of Huizhou (No. 20131226121851953).

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Authors and Affiliations

  1. School of Food, Shihezi University, Shihezi, 832000, People’s Republic of China

    Xiaoxia He & Ya Liu

  2. School of Chemistry and Environmental Engineering, Hanshan Normal University, Chaozhou, 521041, Guangdong, People’s Republic of China

    Yu Chen

  3. Huizhou Research Institute, Sun Yat-sen University, Huizhou, 516081, People’s Republic of China

    Xiaoxia He, Lina Fang, Zeng Chen & Hongbing Ji

  4. School of Chemistry, Fine Chemical Industry Research Institute, Sun Yat-sen University, Guangzhou, 510275, People’s Republic of China

    Yu Chen & Hongbing Ji

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  1. Xiaoxia He
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  2. Yu Chen
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Correspondence to Ya Liu or Hongbing Ji.

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He, X., Chen, Y., Liu, Y. et al. Distribution of Products from Catalytic Conversion of Cellulose Over Metal-Modified Hierarchical H-ZSM-5 in Aqueous Media. Catal Lett 149, 2078–2088 (2019). https://doi.org/10.1007/s10562-019-02795-7

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  • DOI: https://doi.org/10.1007/s10562-019-02795-7

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