Abstract
Ionic liquids (ILs) have shown predominant catalytic activity in the field of catalytic conversion of CO2. Unfortunately, ILs catalysts can be only used in kettle catalysis as homogeneous systems, which suffered from the difficulty in product purification and catalysts recycling so affect their industrial application. In this work, a series of composite ILs were prepared by functionalized imidazolium ILs and lewis acid (ZnBr2). Then composite ILs immobilized on molecular sieve (MCM-22) with chemical bonding to obtain heterogeneous catalysts applied in the reaction of propylene oxide and carbon dioxide to synthesize propylene carbonate. The effects of catalytic temperature, pressure and cycle times on the conversion and yield were studied. The results showed that the optimal catalyst was MCM-22-[CeMIM]Cl/(ZnBr2)2, when the catalytic temperature is 120 °C, the pressure is 2.5 MPa and the dosage of catalyst is 2.0%, the conversion rate is 100%, and selectivity is 97.4%.
Graphical Abstract
Similar content being viewed by others
References
Ren WM, Liu ZW, Wen YQ, Zhang R, Lu XB (2009) J Am Chem Soc 131:11509
He M, Sun Y, Han B (2013) Angew Chem Int Ed 52:9620
Ma R, Zhou YB, He LN (2016) Catal Today 274:35
Zhang WZ, Yang MW, Lu XB (2016) Green Chem 18:4181
Kohrt C, Werner T (2015) ChemSusChem 8:2031
North M, Pasquale R, Young C (2010) Green Chem 12:1514
Dai WL, Chen L, Yin SF, Luo SL, Au CT (2010) Catal Lett 135:295
Fuchs MA, Altesleben C, Staudt SC, Walter O, Zevaco TA, Dinjus E (2014) Catal Sci Technol 4:1658
Song J, Zhang Z, Han B, Hu S, Li W, Xie Y (2008) Green Chem 10:1337
Sadeghzadeh SM (2015) Green Chem 17:3059
Jutz F, Grunwaldt JD, Baiker A (2008) J Mol Catal A 279:94
Decortes A, Castilla AM, Kleij AW (2010) Angew Chem Int Ed 49:9822
Ema T, Miyazaki Y, Shimonishi J, Maeda C, Hasegawa JY (2014) J Am Chem Soc 136:15270
Zhang YG, Chan JYG (2010) Energy Environ Sci 3:408
Wang JQ, Leong JY, Zhang YG (2014) Green Chem 16:4515
Kim MI, Kim DK, Bineesh KV, Kim DW, Selvaraj M, Park DW (2013) Catal Today 200:24
Li FW, Xiao LF, Xia CG, (2005) Chem J Chin Univ 26:343
Bai D, Duan S, Hai L, Jing H (2012) ChemCatChem 4:1752
Wang Y, Sun J, Xiang D, Wang L, Sun J, Xiao FS (2009) Catal Lett 129:437
Liang S, Liu H, Jiang T, Song J, Yang G, Han B (2011) Chem Commun 47:2131
Luo RC, Zhou XT, Fang YX, Ji HB (2015) Carbon 82:1
Lan DH, C L, Au CT, Yin SF (2015) Carbon 93:22
Lan DH, Wang HT, C L, Au CT, Yin SF (2016) Carbon 100:81
Lang XD, Yu YC, Li ZM, He LN (2016) J CO2 Util 15:115
Wang JQ, Sun J, Shi CY, Cheng WG, Zhang XP, Zhang SJ (2011) Green Chem 13:3213
Guo LY, Shi TJ, Li Z, (2011) Eur J Wood Wood Prod 69:383
Guo LY, Ma XY, Zhang B, Wang ZM, Huang PC, (2015) E-Polymers 15:33
Guo LY, Zhang B, Wang ZM, Ma XY, Huang PC, (2015) Acta Polym Sin 5:556
Pourjavadi A, Hosseini SH, Doulabi M, Fakoorpoor SM, Seidi F (2012) ACS Catal 2:1259
Sun J, Cheng WG, Fan W, Wang YH, Meng ZY, Zhang SJ (2009) Catal Today 148:361
Udayakumar S, Raman V, Shim HL, Park DW (2009) Appl Catal A 368:97
Sakai T, Tsutsumi Y, Ema T (2008) Green Chem 10:337
Saptal VB, Bhanage BM (2016) ChemCatChem 8:244
Leng Y, Lu D, Jiang PP, Zhang CJ, Zhao JW, Zhang WJ (2016) Catal Commun 74:99
Jadhav AH, Thorat GM, Lee K, Lim AC, Kang H, Seo JG (2016) Catal Today 265:56
Han L, Li HQ, Choi SJ, Park MS, Lee SM, Kim YJ, Park DW (2012) Appl Catal A 429–430:67
Baj S, Krawczyk T, Jasiak K, Siewniak A, Pawlyta M (2014) Appl Catal A 488:96
Cheng WG, Chen X, Sun J, Wang JQ, Zhang SJ (2013) Catal Today 200:117
Adam F, Appaturi JN, Ng EP (2014) J Mol Catal A 386:42
Kim MI, Choi SJ, Kim DW, Park DW (2014) J Ind Eng Chem 20:3102
Lee EH, Ahn JY, Dharman MM, Park DW, Park SW, Kim I (2008) Catal Today 131:130
Adam F, Balakrishnan S, Wong PL (2006) J Phys Sci 17:1
Adam F, Appaturi JN, Thankappan R, Nawi MAM (2010) Appl Surf Sci 257:811
Appaturi JN, Adam F (2013) Appl Catal B 136–137:150
Valkenberg MH, deCastro C, Hölderich WF (2002) Green Chem 4:88
Xie Y, Ding KL, Liu ZM, Li JJ, An GM, Tao RT, Sun ZY, Yang ZZ, (2010) Chem A Eur J 16:6687
Fujita SI, Nishiura M, Arai M (2010) Catal Lett 135:263
Xiao LF, Li FW, Peng JJ, Xia CG (2006) J Mol Catal A 253:265
Son YS, Park SW, Park DW, Oh KJ, Kim SS (2009) Korean J Chem Eng 26:783
Udayakumar S, Lee MK, Shim HL, Park DW (2009) Appl Catal A 365:88
Acknowledgements
This work was supported by National Natural Science Foundation of China and Natural Science Foundation of Liaoning province of China (201602537).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Guo, L., Deng, L., Jin, X. et al. Composite Ionic Liquids Immobilized on MCM-22 as Efficient Catalysts for the Cycloaddition Reaction with CO2 and Propylene Oxide. Catal Lett 147, 2290–2297 (2017). https://doi.org/10.1007/s10562-017-2137-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-017-2137-y