Abstract
Basic nanospace was synthesized by the homogeneous modification of FSM-16 with 3-(triethoxysilyl)pyridine, which is a rigid substrate without an alkyl chain as linker. Aldol condensation of butanal gave the corresponding dimer in high yields over 3-(triethoxysilyl)pyridine-modified FSM-16. A copper-pyridine complex was immobilized within the interior of FSM-16 using the modified pyridyl group as a ligand and the oxidative coupling polymerization of 2,5-dimethylphenol proceeded with high regio-selectivity.
Graphical Abstract
Basic nanospace was synthesized by the homogeneous modification of FSM-16 with 3-(triethoxysilyl)pyridine, which is a rigid substrate without an alkyl chain as linker. Aldol condensation of n-butyraldehyde gave the corresponding dimer in high yields over 3-(triethoxysilyl)pyridine-modified FSM-16. A copper-pyridine complex was immobilized within the interior of FSM-16 using a modified pyridyl group as the ligand and the oxidative polymerization of 2,5-dimethylphenol proceeded with high regio-selectivity.
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Acknowledgments
The high-purity water glass was kindly supplied from Fuji Silysia Chem. Co. Ltd. TT acknowledges the Grant-in-Aid for Scientific Research for Challenging Exploratory Research (no. 10012401) under Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan. KT is supported by Program for Improvement of Research Environment for Young Researchers from Special Coordination Funds for Promoting Science and Technology (SCF) commissioned by the Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan.
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Shishido, T., Kawaguchi, T., Iwashige, T. et al. Synthesis and Catalytic Performance of Organic–Inorganic Hybrid Mesoporous Material Having Basic Nanospace. Catal Lett 140, 121–126 (2010). https://doi.org/10.1007/s10562-010-0456-3
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DOI: https://doi.org/10.1007/s10562-010-0456-3