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Sulfur-Reducing Additives Based on Aluminosilicates Al-SBA-15 and Al-SBA-16 for Cracking catalysts

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Chemistry and Technology of Fuels and Oils Aims and scope

Sulfur-reducing additives for fluid catalytic cracking (FCC) catalysts based on mesoporous aluminosilicates Al-SBA-15 and Al-SBA-16 were synthesized and characterized using FTIR spectroscopy, transmission electron microscopy, low-temperature N2 adsorption/desorption, and thermally programmed desorption of NH3. Catalytic experiments were performed using a commercial zeolite-containing FCC catalyst and the additives (10 wt.%). It was found that all synthesized materials were active for reducing sulfur in liquid catalytic cracking products. The S content in the liquid cracking products obtained using an additive of 3% La-Al-SBA-15/Al2O3 (50:50) decreased by 36% as compared to the same parameter obtained using the commercial catalyst with no additive.

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Acknowledgments

The work was sponsored by a grant of the Russian Science Foundation (Project No. 17-79-10301).

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Authors and Affiliations

  1. I. M. Gubkin Russian State University of Oil and Gas, Moscow, Russia

    A. P. Glotov, N. S. Levshakov, M. I. Artemova, E. M. Smirnova & A.V. Vutolkina

  2. M. V. Lomonosov Moscow State University, Moscow, Russia

    S. V. Lysenko

Authors
  1. A. P. Glotov
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  2. N. S. Levshakov
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  3. M. I. Artemova
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  4. E. M. Smirnova
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  5. A.V. Vutolkina
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  6. S. V. Lysenko
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Corresponding author

Correspondence to A. P. Glotov.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 12 – 16, January – February, 2018.

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Glotov, A.P., Levshakov, N.S., Artemova, M.I. et al. Sulfur-Reducing Additives Based on Aluminosilicates Al-SBA-15 and Al-SBA-16 for Cracking catalysts. Chem Technol Fuels Oils 54, 15–23 (2018). https://doi.org/10.1007/s10553-018-0892-0

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  • DOI: https://doi.org/10.1007/s10553-018-0892-0

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