Skip to main content
Log in

Optimising batch adsorbers for the removal of zinc from effluents using a sodium diimidoacetate ion exchange resin

  • Published:
Adsorption Aims and scope Submit manuscript

Abstract

An ion exchange resin, based on the sodium diimidoacetate structure, has been tested for the removal of zinc ions from effluents. After employing three isotherm models, namely, Langmuir, Freundlich and Langmuir–Freundlich to measure and analyse equilibrium isotherms, a series of agitated batch experiments have been carried out to optimise the removal of zinc ions in a two-stage batch system. The first optimisation model involves minimising the total amount of resin required to achieve a specific percentage zinc removal. The second optimisation study involves minimising the total batch contact time to achieve a certain percentage zinc removal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  • Abdelwahab, O., Amin, N.K., El-Ashtoukhy, E.-S.Z: Removal of zinc ions from aqueous solution using a cation exchange resin. Chem. Eng. Res. Des. 91, 165–173 (2013)

    Article  CAS  Google Scholar 

  • Cheung, C.W., Porter, J.F., McKay, G.: Sorption kinetics for the removal of copper and zinc from effluents using bone char. Sep. Purif. Technol. 19, 55–64 (2000)

    Article  CAS  Google Scholar 

  • Franco, P.E., Veit, M.T., Borba, C.E., Gonçalves, G. da C., Fagundes-Klen, M.R., Bergamasco, R., da Silva, E.A., Suzaki, P.Y.R: Nickel(II) and zinc(II) removal using Amberlite IR-120 resin: ion exchange equilibrium and kinetics. Chem. Eng. J. 221, 426–435 (2013)

    Article  CAS  Google Scholar 

  • Freundlich, H.: Uber die Adsorption in Losungen. Zeitschrift Fur Phys. Chemie. 57, 385–471 (1906).

    CAS  Google Scholar 

  • Fu, F., Wang, Q.: Removal of heavy metal ions from wastewaters: a review. J. Environ. Manage. 92, 407–418 (2011)

    Article  CAS  Google Scholar 

  • Ho, Y.S., McKay, G.: Pseudo-second order model for sorption processes. Process. Biochem. 34, 451–465 (1999)

    Article  CAS  Google Scholar 

  • Jain, R., Jordan, N., Schild, D., van Hullebusch, E.D., Weiss, S., Franzen, C., Farges, F., Hübner, R., Lens, P.N.L: Adsorption of zinc by biogenic elemental selenium nanoparticles. Chem. Eng. J. 260, 855–863 (2015)

    Article  CAS  Google Scholar 

  • Kumar, J., Balomajumder, C., Mondal, P.: Application of agro-based biomasses for zinc removal from wastewater—a review. CLEAN 39, 641–652 (2011).

    CAS  Google Scholar 

  • Langmuir, I.: The constitution and fundamental properties of solids and liquids. part 1. solids. J. Am. Chem. Soc. 38, 2221–2295 (1916)

    Article  CAS  Google Scholar 

  • Lerch, R.G., Ratkowsky, D.A.: Optimum allocation of adsorbent in stagewise adsorption operations. Ind. Eng. Chem. Fundam. 6, 308–310 (1967)

    Article  CAS  Google Scholar 

  • Malamis, S., Katsou, E.: A review on zinc and nickel adsorption on natural and modified zeolite, bentonite and vermiculite: examination of process parameters, kinetics and isotherms. J. Hazard. Mater. 252–253, 428–461 (2013)

    Article  Google Scholar 

  • McKay, G.: Solution to the homogeneous surface diffusion model for batch adsorption systems using orthogonal collocation. Chem. Eng. J. 81, 213–221 (2001)

    Article  CAS  Google Scholar 

  • Mckay, G., Allen, S.J.: Surface mass transfer processes using peat as an adsorbent for dyestuffs. Can. J. Chem. Eng. 58, 521–526 (1980)

    Article  CAS  Google Scholar 

  • Morcali, M.H., Zeytuncu, B., Baysal, A., Akman, S., Yucel, O.: Adsorption of copper and zinc from sulfate media on a commercial sorbent. J. Environ. Chem. Eng. 2, 1655–1662 (2014)

    Article  CAS  Google Scholar 

  • Nagajyoti, P.C., Lee, K.D., Sreekanth, T.V.M: Heavy metals, occurrence and toxicity for plants: a review. Environ. Chem. Lett. 8, 199–216 (2010)

    Article  CAS  Google Scholar 

  • Ng, J.C.Y., Cheung, W.H., McKay, G.: Equilibrium Studies of the Sorption of Cu(II) Ions onto Chitosan. J. Colloid Interface Sci. 255, 64–74 (2002)

    Article  CAS  Google Scholar 

  • Roohani, N., Hurrell, R., Kelishadi, R., Schulin, R.: Zinc and its importance for human health: an integrative review. J. Res. Med. Sci. 18, 144–157 (2013).

    Google Scholar 

  • Sdiri, A.T., Higashi, T., Jamoussi, F.: Adsorption of copper and zinc onto natural clay in single and binary systems. Int. J. Environ. Sci. Technol. 11, 1081–1092 (2014)

    Article  CAS  Google Scholar 

  • Shek, T.-H., Ma, A., Lee, V.K.C., McKay, G.: Kinetics of zinc ions removal from effluents using ion exchange resin. Chem. Eng. J. 146, 63–70 (2009)

    Article  CAS  Google Scholar 

  • Sips, R.: On the Structure of a Catalyst Surface. J. Chem. Phys. 16, 490–495 (1948)

    Article  CAS  Google Scholar 

  • Song, J., Zhang, R., Li, K., Li, B., Tang, C.: Adsorption of Copper and Zinc on Activated Carbon Prepared from Typha latifolia L. CLEAN. 43(1), 79–85 (2014).

    Google Scholar 

  • Taute, J.J., Sole, K.C., Hardwick, E.: Removal of zinc from a base-metal solution using ion exchange at Rustenburg Base Metal Refiners. J. Chem. Technol. Biotechnol. 89, 919–926 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge support from Hong Kong Productivity Council and Hong Kong Research Grants Council. The authors would also like to thank the National Elites Foundation of Iran for their support of the lead author.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Alireza Bazargan or Gordon McKay.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bazargan, A., Shek, TH., Hui, CW. et al. Optimising batch adsorbers for the removal of zinc from effluents using a sodium diimidoacetate ion exchange resin. Adsorption 23, 477–489 (2017). https://doi.org/10.1007/s10450-016-9857-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10450-016-9857-y

Keywords

Navigation