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Electronic structure of LiMnO : X-ray emission and photoelectron spectra and band structure calculations

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Abstract:

The electronic structure of LiMnO2 and Li2MnO3 was studied by means of X-ray photoelectron and soft X-ray emission spectroscopy. For LiMnO2, LSDA and LSDA+U calculations were carried out. The LSDA+U calculations are in rather good agreement with the measured valence-band structure as well as with the magnetic and electrical properties of LiMnO2. It is shown that the band gap in LiMnO2 is determined by the charge-transfer effect.

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Authors and Affiliations

  1. Institute of Metal Physics, Russian Academy of Sciences - Ural Division, 620219 Yekaterinburg GSP-170, Russia, , , , , , RU

    V.R. Galakhov, M.A. Korotin, N.A. Ovechkina & E.Z. Kurmaev

  2. Institute of Solid State Chemistry, Russian Academy of Sciences - Ural Division, 620219 Yekaterinburg GSP-145, Russia, , , , , , RU

    V.S. Gorshkov & D.G. Kellerman

  3. University of Osnabrück - Fachbereich Physik, 49069 Osnabrück, Germany, , , , , , DE

    S. Bartkowski & M. Neumann

Authors
  1. V.R. Galakhov
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  2. M.A. Korotin
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  3. N.A. Ovechkina
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  4. E.Z. Kurmaev
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  5. V.S. Gorshkov
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  6. D.G. Kellerman
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  7. S. Bartkowski
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  8. M. Neumann
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Additional information

Received 15 March 1999 and Received in final form 14 July 1999

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Galakhov, V., Korotin, M., Ovechkina, N. et al. Electronic structure of LiMnO : X-ray emission and photoelectron spectra and band structure calculations. Eur. Phys. J. B 14, 281–286 (2000). https://doi.org/10.1007/s100510050130

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  • DOI: https://doi.org/10.1007/s100510050130

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