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Conflicting roles of Na-doped layered cathode material LiCoO2 for Li-ion batteries

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Abstract

In this work, the electrochemical performance of Na-doped layered cathode material LiCoO2 for Li-ion batteries is studied using first-principles calculations. The results show that the doped Na ion acts as a pillar, which can greatly increase the diffusion rate of Li ions, but it is not conducive to improving cycle performance and delithiation potential. These research results provide a theoretical reference for the study of Li-ion batteries with high-rate performance. Due to the conflicting role of single element doping, the multi-element co-doping strategy will be the best way to develop high-performance Li-ion batteries.

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Funding

This work was supported by the Scientific Research Fund of Jiangxi Provincial Education Department (Grant No. GJJ191211).

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Authors and Affiliations

  1. Yuzhang Normal University, Nanchang, 330103, People’s Republic of China

    Yongzhong Chen & Wei Hu

  2. Jiangxi University of Technology, Nanchang, 330098, People’s Republic of China

    Qinghua Zhou

  3. Jiangxi University of Chinese Medicine, Nanchang, 330004, People’s Republic of China

    Huili Li

Authors
  1. Yongzhong Chen
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  2. Wei Hu
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  3. Qinghua Zhou
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  4. Huili Li
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Correspondence to Wei Hu or Huili Li.

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Chen, Y., Hu, W., Zhou, Q. et al. Conflicting roles of Na-doped layered cathode material LiCoO2 for Li-ion batteries. J Solid State Electrochem 25, 2565–2569 (2021). https://doi.org/10.1007/s10008-021-05032-7

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  • DOI: https://doi.org/10.1007/s10008-021-05032-7

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