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Towards stabilization of the potential response of Mn(III) tetraphenylporphyrin-based solid-state electrodes with selectivity for salicylate ions

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Abstract

We report a new type of solid-state electrode (type I) of a simple design with polyvinyl chloride membranes based on Mn(III) tetraphenylporphyrin and with graphite as the electronically conducting substrate. Enlargement of the membrane/graphite contact area by soaking graphite in the plasticizer with subsequent conditioning of the electrode at 30 °C allowed us to shorten the time required to achieve steady potential values of the sensors to just 3 days. These electrodes do not require a specially added RedOx system in the transducer layer. Stabilization of the EMF response of type I electrodes is compared to type II electrodes which contain a Cu0/Cu2+ RedOx couple in the transducer layer. Type I sensors are suitable for measuring the salicylate ion concentration in the clinically important concentration range down to 2.5 × 10−4 M with a sensitivity to salicylate ion of −59.0 mV decade−1 in solutions with a high constant background of chloride ions of 0.12 M at pH = 5.3, making this a promising technique for an effective design of solid-contact ion-selective electrodes with polymeric sensing membranes.

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Acknowledgements

The authors acknowledge Saint-Petersburg State University for a research grant 12.38.218.2015. The Resource Educational Center of the St. Petersburg State University in chemistry is acknowledged for the scanning electron microscopy investigations.

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Authors and Affiliations

  1. St. Petersburg State University of Industrial Technologies and Design, 191186, St. Petersburg, Bol’shaya Morskaya, 18, Russia

    Tatiana A. Skripnikova

  2. St. Petersburg State University, 198504, St. Petersburg, 7-9 Universitetskaya nab, Russia

    Anna A. Starikova, Galina I. Shumilova, Yuri E. Ermolenko & Andrey A. Pendin

  3. Peter Grünberg Institute PGI-8, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany and JARA-FIT, 52425, Jülich, Germany

    Yulia G. Mourzina

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  1. Tatiana A. Skripnikova
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  2. Anna A. Starikova
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  3. Galina I. Shumilova
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  4. Yuri E. Ermolenko
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  5. Andrey A. Pendin
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  6. Yulia G. Mourzina
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Skripnikova, T.A., Starikova, A.A., Shumilova, G.I. et al. Towards stabilization of the potential response of Mn(III) tetraphenylporphyrin-based solid-state electrodes with selectivity for salicylate ions. J Solid State Electrochem 21, 2269–2279 (2017). https://doi.org/10.1007/s10008-017-3575-6

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