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Redox-active silica nanoparticles. Part 4. Synthesis, size distribution, and electrochemical adsorption behavior of ferrocene- and (diamine)(diphosphine)-ruthenium(II)-modified Stöber silica colloidal particles

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Abstract

Stöber silica nanoparticles with a diameter of approximately 800 nm are covalently modified by redox-active ferrocene or (diamine)(diphosphine) ruthenium(II) units attached to a spacer. The particles are characterized by NMR spectroscopic and chemical techniques. Two variants of modification by condensation are compared. Besides an estimation of the size and the particle porosity, the agglomeration behavior in solvents of different polarity is investigated. The adsorption of the particles to an electrode surface is followed.

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Notes

  1. The procedure for preparation of 3 has been described previously in [53]. Inadvertently, an essential part of the procedure was omitted, and therefore, full details are given here.

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Acknowledgements

We thank the Deutsche Forschungsgemeinschaft for support of this work within the Graduiertenkolleg 441 “Chemie in Interphasen,” as well as the Max–Buchner–Forschungsstiftung and the Marie Curie training site “SurFace” for providing fellowships to F.N. We acknowledge possibilities to record BET measurements in the Center for Applied Geosciences, Universität Tübingen (Professor Dr. P. Grathwohl, Dr. T. Wendel, and Ms. A. Walz), and SEM pictures in the Institut für Physik, Universität Tübingen (Professor Dr. E. Plies, Ms. Dorothea Adam). We thank Professor Dr. H.-J. Meyer and Ms. Ruth Schmitt (Institut für Anorganische Chemie, Universität Tübingen) for the use of instrumentation and the uncomplicated technical assistance concerning powder X-ray experiments.

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Authors and Affiliations

  1. Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany

    Filip Novak, Nicolas Plumeré, Bernd Schetter, Bernd Speiser, Diana Straub, Klaus Albert, Gerd Fischer & Christoph Meyer

  2. Institut für Anorganische Chemie, Universität Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany

    Hermann A. Mayer & Michaela Reginek

  3. Institut für Physikalische und Theoretische Chemie, Universität Tübingen, Auf der Morgenstelle 8, 72076, Tübingen, Germany

    Hans-Joachim Egelhaaf

  4. Institutt for materialteknologi, NTNU, Sem Sælands vei 6, 7491, Trondheim, Norway

    Børre Børresen

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  1. Filip Novak
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Correspondence to Bernd Speiser.

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Part 3: see, ref. [1]

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Novak, F., Plumeré, N., Schetter, B. et al. Redox-active silica nanoparticles. Part 4. Synthesis, size distribution, and electrochemical adsorption behavior of ferrocene- and (diamine)(diphosphine)-ruthenium(II)-modified Stöber silica colloidal particles. J Solid State Electrochem 14, 289–303 (2010). https://doi.org/10.1007/s10008-009-0811-8

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