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Template synthesis and electrotransport behavior of polymer composites based on perfluorinated membranes incorporating polyaniline

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Abstract

A method of chemical template synthesis is described for producing composites based on a perfluorinated matrix with polyaniline chains implanted. It has been shown that the choice of experimental and conditioning techniques is relevant for the composites’ investigation. The conductivity, diffusion permeability, selectivity, and electroosmotic permeability of the composites have been investigated in comparison with the same properties of the initial MF-4SC membrane. A model describing the transport behavior of the composites in the doped state as a fibrous-cluster system is proposed. A set of transport and structural parameters of the composites in a H2SO4 solution has been calculated and an analysis of the results observed has been carried out. The set of electrotransport properties is explained by the morphological features of the composites, taking into account the redox heterogeneity of polyaniline. The contribution of electron conductivity to the mixed conductivity of composites with a certain saturation degree by polyaniline has been estimated.

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Acknowledgements

The authors are grateful to the Russian Foundation for Basic Research and Krasnodar Region Administration for the financial support of this work. The authors express their gratitude to Dr. Jaroslav Sytchev (University of Miskolc, Hungary) for his valuable help with the work on this paper.

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Authors and Affiliations

  1. Department of Physical Chemistry, Kuban State University, 149, Stavropolskaya St., Krasnodar, 350040, Russia

    Ninel P. Berezina & Anna A. Kubaisy

  2. JSC “Plastpolymer”, 32, Polyustrovski Ave., St.-Petersburg, 195197, Russia

    Sergey V. Timofeev

  3. Karl-Franzens-University, Heinrichstrasse 28, Graz, 8010, Austria

    Larisa V. Karpenko

Authors
  1. Ninel P. Berezina
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  2. Anna A. Kubaisy
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  3. Sergey V. Timofeev
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  4. Larisa V. Karpenko
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Correspondence to Ninel P. Berezina.

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Berezina, N.P., Kubaisy, A.A., Timofeev, S.V. et al. Template synthesis and electrotransport behavior of polymer composites based on perfluorinated membranes incorporating polyaniline. J Solid State Electrochem 11, 378–389 (2007). https://doi.org/10.1007/s10008-006-0159-2

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  • DOI: https://doi.org/10.1007/s10008-006-0159-2

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