Abstract
This paper describes the history and scheme of reference materials and standard solutions for titrimetry in Japan. Titrimetry is one of the most fundamental and precise methods for determination of a constituent, based on the effective purity of reference materials in stoichiometric analysis. It has wide-ranging applications based on titrimetric reactions such as neutralization, redox, chelatometric, and precipitation titration processes, which are used in various analytical fields all over the world. Japanese Industrial Standards (JIS) have played an important role in establishing a stable supply of reference materials for titrimetry since the 1950s. There are several reports of preparations and their determination, including coulometric studies, in order to establish highly reliable reference materials. This paper briefly reviews the schemes and studies of standardization through the provision of reference materials and standard solutions based on JIS, and several applications in other standards.
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References
Kolthoff IM, Sandell EB, Meehan EJ, Bruckenstein S (1969) Quantitative chemical analysis. The Macmillan Company Collier-Macmillan, London
Kolthoff IM, Belcher R (1957) Titration methods: oxidation-reduction reactions. In: Volumetric analysis, vol 3. Interscience Publishers, New York
National Institute of Technology, Evaluation, Japan Reagent Association (2003) Shiyaku guide book (in Japanese), 3d edn., The Chemical Daily, Tokyo
ISO/IEC 17011 (2004) Conformity assessment—general requirements for accreditation bodies accrediting conformity assessment bodies. ISO, Geneva
JIS K 8001 (2003) General rule for test methods of reagents. Japanese Industrial Standards Committee, Tokyo
JIS K 8007 (2003) General rule for test methods of highly purified reagents. Japanese Industrial Standards Committee, Tokyo
JIS K 8008 (2006) General rules for biochemical reagents. Japanese Industrial Standards Committee, Tokyo
American Chemical Society (2000) ACS-specifications reagent chemicals, 9th edn. Oxford University Press, New York
Merck KGaA (1972) Merck standard. Merck, USA
Hopkin & Williams Ltd, the British Drug Houses Ltd, Merck (1984) AnalaR, 8th edn. AnalaR Standards Ltd, London
ISO 6353-2 (1983) Reagents for chemical analysis—Part 2. Specifications, first series. ISO, Geneva
ISO 6353-3 (1983) Reagents for chemical analysis—Part 3. Specifications, second series. ISO, Geneva
JIS K 8005 (2006) Reference materials for volumetric analysis. Japanese Industrial Standards Committee, Tokyo
ISO/IEC 17025 (2005) General requirements for the competence of testing and calibration laboratories. ISO, Geneva
P. R. China Standard, GB 10730 (1989) Primary chemical—potassium hydrogen phthalate. Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 10731 (1989) Primary chemical—potassium dichromate. Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 10732 (1989) Primary chemical—potassium chloride. Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 10733 (1989) Primary chemical—sodium chloride. Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 10734 (1989) Primary chemical—ethylenediaminetetraacetic acid disodium salt. Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 10735 (1989) Primary chemical—sodium carbonate. Quality Supervision and Inspection and Quarantine, Beijing
Tang G, Lin D (1980) Acta Metrol Sin (in Chinese) 1:142–146
Tang G, Lin D (1981) Acta Metrol Sin (in Chinese) 2:233–237
Tang G, Lin D, Li Z (1985) Acta Metrol Sin (in Chinese) 6:50–54
P. R. China Standard, GB 10737 (2007) Working chemical—general rules for assay—weight titration (potentiometric method). Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 10738 (2007) Working chemical—general rules for assay—weight titration. Quality Supervision and Inspection and Quarantine, Beijing
P. R. China Standard, GB 1253 (1989), GB 1254 (1990), GB 1255 (2007), GB 1256 (1990), GB 1257 (1989), GB 1258 (1990), GB 1259 (2007), GB 1260 (1990), GB 10736 (1989), GB 12593 (1990), GB 12594 (1990), GB 12595 (1990), GB 12596 (1990), GB 12597 (1990) Working chemical. Quality Supervision and Inspection and Quarantine, Beijing
Valid Analytical Measurement (1995) The VAM bulletin, No. 12. Laboratory of the Government Chemist, UK
Valid Analytical Measurement (1995) The VAM bulletin, No. 13. Laboratory of the Government Chemist, UK
King B (1997) Metrologia 34:77–82
Lingane JJ (1954) Anal Chem 26:622–626
Parsons JS, Seaman W, Amick RM (1955) Anal Chem 27:1754–1756
Pitts JN, DeFord DD Jr, Martin TW, Schmall EA (1954) Anal Chem 26:628–631
Taylor JK, Smith SW (1959) J Res Natl Bur Std 63A:153–159
Commission on Electroanalytical Chemistry (1976) Pure Appl Chem 45:125–130
Mohr PJ, Taylor BN, Newell DB (2007) CODATA recommended values of the fundamental physical constants. National Institute of Standards and Technology, USA
Yoshimori T, Tanaka T (1973) Jpn Anal (in Japanese) 22:1251–1260
Yoshimori T, Tanaka T (1976) Bunseki (in Japanese) 9:590–597
Máriássy M, Vyskočil L, Mathiasová A (2000) Accred Qual Assur 5:437–440
Brown R, Milton M, Brewer P, Wielgosz R (2001) NPL Report COAM 5
Ma L (2002) Accred Qual Assur 7:163–167
Brown R, Milton M, Brewer P (2003) NPL Report COAM 18
Felber H, Rezzonico S, Máriássy M (2003) Metrologia 40:249–254
Recknagel S, Breitenbach M, Pautz J, Lück D (2007) Anal Chim Acta 599:256–263
Yoshimori T, Tanaka T (1971) Anal Chim Acta 55:185–191
Yoshimori T, Tanaka T (1973) Anal Chim Acta 66:85–91
Yoshimori T, Tanaka T, Ogawa M, Horikoshi T (1973) Anal Chim Acta 63:351–357
Yoshimori T, Sakaguchi N (1975) Talanta 22:233–238
Yoshimori T (1975) Talanta 22:827–835
Yoshimori T (1982) Bunseki Kagaku 31:E343–E359
Yoshimori T, Kamijoh K (1982) Talanta 29:343–344
Certified reference materials’ certificates provided by BAM, EMPA, NIM (NRCCRM), NIST and SMU
Asakai T, Minegishi R, Inaba N, Ishimura Y, Murayama M, Tanaka T (2006) Anal Sci 22:461–463
Asakai T, Ogura T, Murayama M, Tanaka T (2008) Bunseki Kagaku (in Japanese) 57:49–53
Yoshimori T, Hino Y, Takeuchi T (1966) Jpn Anal (in Japanese) 15:1234–1238
Yoshimori T, Tanaka T (1979) Bull Chem Soc Jpn 52:1366–1367
Yoshimori T, Hikawa I (1967) Jpn Anal (in Japanese) 16:927–930
Yoshimori T, Matsubara I, Hirosawa K, Tanaka T (1970) Jpn Anal (in Japanese) 19:681–687
Yoshimori T, Matsubara I (1969) Bull Chem Soc Jpn 43:2800–2804
Hioki A, Kokubun A, Kubota M (1994) Analyst 119:1879–1882
Asakai T, Murayama M, Tanaka T (2007) Accred Qual Assur 12:151–155
Hioki A, Asakai T (2002) TR Z 0020: purity determination method for high-purity materials by acidimetric coulometric titration. Japanese Industrial Standards Technical Report, Japanese Industrial Standards Committee, Tokyo
Hioki A, Asakai T (2002) TR Z 0021: purity determination method for high-purity materials by oxidimetric coulometric titration. Japanese Industrial Standards Technical Report, Japanese Industrial Standards Committee, Tokyo
Asakai T, Murayama M, Tanaka T (2007) Talanta 73:346–351
Asakai T, Kakihara Y, Kozuka Y, Hossaka S, Murayama M, Tanaka T (2006) Anal Chim Acta 567:269–276
Asakai T, Hara H, Murayama M, Tanaka T (2006) Anal Sci 22:1121–1124
Tanaka T, Hotta K, Yoshimori T (1980) Bull Chem Soc Jpn 53:661–663
Tanaka T, Takahashi A, Kobayashi S, Mizuike A (1993) Anal Sci 9:455–457, 535–538
Tanaka T, Kurooka K, Ikeda K, Ogura T (1998) Nihon Kagakukaishi (in Japanese) 8:535–538
Tanaka T, Hayashi H, Komiya Y, Nabekawa H, Hayashi H (2007) Bunseki Kagaku (in Japanese) 56:327–332
Yoshimori T, Matsubara I, Tanaka T, Yoshida K, Tanaka K, Tanabe T (1971) Bull Chem Soc Jpn 44:734–737
Katoh M, Yoshimori T (1972) Talanta 19:407–414
Tanaka T, Hasegawa H, Oishi K (1984) Bunseki Kagaku 33:E9–E15
Hioki A, Kubota M, Kawase A (1991) Talanta 38:397–404
Hioki A, Kubota M, Kawase A (1992) Analyst 117:997–1001
Tanaka T, Shutto E, Mizoguchi T, Fukushima K (2001) Anal Sci 17:277–280
Special Committee for Intellectual Infrastructure Development (1998) For improvement of intellectual infrastructure in Japan (in Japanese)
Special Committee for Intellectual Infrastructure Development (2002) Special committee for intellectual infrastructure development report 2002 revision (in Japanese)
Science Council of Japan (2003) Development of reference materials concerning biotechnology-based medicines and human healthcares (in Japanese)
Asakai T (2004) J Metrol Soc India 19:219–238
Kubota M, Kato K, Hioki A, Iijima H, Matsumoto Y (1997) Accred Qual Assur 2:130–136
Kubota M (2000) Anal Sci 16:445–447
Bureau International des Poids et Mesures/Comité Consultatif pour la Quantité de Matière—métrologie en chimie (BIPM/CCQM). http://www1.bipm.org/en/committees/cc/ccqm/
Reference Materials Total Information Services of Japan (RMinfo) provided by the National Institute of Technology and Evaluation (NITE). http://www.rminfo.nite.go.jp/
Naito N, Ishikawa H, Yamauchi Y, Murayama M (2003) Accred Qual Assur 8:26–29
The International Database for Certified Reference Materials (COMAR) provided by the Federal Institute for Materials Research and Testing (BAM). http://www.comar.bam.de/
Pradel R, Steiger T, Klich H (2003) Accred Qual Assur 8:317–318
Pradel R, Steiger T (2007) Accred Qual Assur 12:265–268
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Asakai, T., Murayama, M. Scheme and studies of reference materials for volumetric analysis in Japan. Accred Qual Assur 13, 351–360 (2008). https://doi.org/10.1007/s00769-008-0375-9
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DOI: https://doi.org/10.1007/s00769-008-0375-9