Summary.
The reaction of elemental antimony with elemental sulfur and [Ph4P]Br in an aqueous solution of neopentanediamine under solvothermal conditions yields yellow needles of the new thioantimonate(III) [Ph4P]2[Sb6S10]. The structure consists of [Ph4P]+ cations and infinite one-dimensional anionic (Sb6S10 2−)n chains running along the crystallographic a axis. The chains are composed of 10-membered Sb5S5 rings with alternating Sb and S atoms and separated by the tetraphenylphosphonium cations. Upon heating the compound decomposes in two distinct steps, starting at about 100°C. The final product was identified by X-ray powder diffractometry as Sb2S3.
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Received December 17, 1999. Accepted (revised) February 7, 2000
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Rijnberk, H., Näther, C. & Bensch, W. Solvothermal Synthesis, Crystal Structure Determination, and Properties of the Thioantimonate [Ph4P]2[Sb6S10]. Monatshefte fuer Chemie 131, 721–726 (2000). https://doi.org/10.1007/s007060070072
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DOI: https://doi.org/10.1007/s007060070072