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Solvothermal Syntheses and Characterization of Three New Thioantimonates Combined with Lanthanide Complexes

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Abstract

Three lanthanide thioantimonates [Ho(en)4]SbVS4·0.5en (1, en = ethylenediamine) and [Ln(teta)(en)SbVS4] [Ln = Ho (2), Y (3), teta = triethylenetetramine] were prepared under mild solvothermal conditions and structurally characterized. 1 consists of isolated [Ho(en)4]3+ ion, tetrahedral [SbVS4]3− ion, and free en molecule. Both 2 and 3 contain neutral lanthanide-centred complex, where the tetrahedral anion [SbVS4]3− acts as a chelating ligand to complex [Ln(en)(teta)]3+ cation. Density functional theory calculations for both 2 and 3 have been performed, and the band gaps of 2.02 eV for 1, 1.78 eV for 2 and 1.83 eV for 3 have been derived from optical absorption.

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Acknowledgments

This work was supported by the NNSF of china (No. 21163022), the NSF of Chongqing municipality (No. cstc2014jcyjA50002), the Key Project of Chinese Ministry of Education (No. 212132), the NSF of Guangxi Province (2014GXNSFBB118002) and Program for Excellent Talents in Chongqing Higher Education Institutions. The authors are also grateful to Chongqing Normal University for financial support (13XLZ07), the Innovative Training Program of University Student (201410637004) and the Science Research and Technology Development Project of Yulin City, Guangxi Province(Grant: 1371001).

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Authors and Affiliations

  1. College of Chemistry, Chongqing Normal University, Chongqing, 401331, People’s Republic of China

    Ligang Zhu, Xing Liu, Jian Zhou, Liu Yang, Rongqing Zhao, Yu Hui & Shimei Tang

  2. College of Chemistry and Material, Yulin Normal University, Yulin, 537000, People’s Republic of China

    Ligang Zhu

  3. Chongqing Key Laboratory of Photo-Electric Functional Materials, Chongqing, 401331, People’s Republic of China

    Jian Zhou

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  1. Ligang Zhu
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Correspondence to Xing Liu or Jian Zhou.

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Zhu, L., Liu, X., Zhou, J. et al. Solvothermal Syntheses and Characterization of Three New Thioantimonates Combined with Lanthanide Complexes. J Clust Sci 26, 1333–1341 (2015). https://doi.org/10.1007/s10876-014-0817-y

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  • DOI: https://doi.org/10.1007/s10876-014-0817-y

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