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Supramolecular assembly of copper(II) halogenobenzoates with nicotinamide into hydrogen-bonding networks

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Abstract

Nicotinamide has been employed as a supramolecular reagent in the synthesis of ten copper(II) chloro-, bromo-, fluoro-, iodo-, and dichlorobenzoate complexes. Compound structures were determined by single-crystal X-ray diffraction structural analysis. All ten compounds are monomeric complexes with a square-bipyramidal coordination sphere around the Cu2+ ion. The two polymorphs of [Cu(2,6-Cl2bz)2(nia)2] are examples of coordination compounds which are conformation and supramolecular isomers. The molecules of all compounds are connected by N–H…O and O–H…O hydrogen bonds from NH2 groups of nicotinamide and water molecules which create supramolecular hydrogen-bonding-coordination chains and networks.

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Acknowledgements

Slovak Grant agencies (VEGA 1/0639/18, VEGA 1/0686/17 and APVV-14-0078, APVV-15-0079, APVV-16-0039) are acknowledged for the financial support.

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Authors and Affiliations

  1. Faculty of Chemical and Food Technology, Slovak University of Technology, 81237, Bratislava, Slovakia

    Jozef Halaška, Marian Koman, Marian Valko & Jan Moncol

  2. Faculty of Chemistry and Chemical Technology, University of Ljubljana, 1000, Ljubljana, Slovenia

    Andrej Pevec & Bojan Kozlevčar

  3. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10, Pardubice, Czech Republic

    Zdeňka Růžičková

  4. Department of Chemistry, Faculty of Natural Sciences, Constantine the Philosopher University, 94974, Nitra, Slovakia

    Michael K. Lawson

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  1. Jozef Halaška
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  2. Andrej Pevec
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  4. Michael K. Lawson
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  5. Marian Koman
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  8. Jan Moncol
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Correspondence to Jan Moncol.

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Halaška, J., Pevec, A., Růžičková, Z. et al. Supramolecular assembly of copper(II) halogenobenzoates with nicotinamide into hydrogen-bonding networks. Monatsh Chem 149, 1017–1030 (2018). https://doi.org/10.1007/s00706-018-2173-3

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  • DOI: https://doi.org/10.1007/s00706-018-2173-3

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