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Complexation of Pb2+ with beauvericin: an experimental and theoretical study

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Abstract

From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of the beauvericin · Pb2+ complex species dissolved in nitrobenzene saturated with water was determined. By using quantum mechanical density functional level of theory calculations, the most probable structure of this complex was derived.

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References

  1. Hamill RL, Higgens CE, Boaz HE, Gorman M (1969) Tetrahedron Lett 10:4255

    Article  Google Scholar 

  2. Logrieco A, Moretti A, Castella G, Kostecki M, Golinski P, Ritieni A, Chelkowski J (1998) Appl Environ Microbiol 64:3084

    CAS  Google Scholar 

  3. Logrieco A, Rizzo A, Ferracane R, Ritieni A (2002) Appl Environ Microbiol 68:82

    Article  CAS  Google Scholar 

  4. Jestoi M, Rokka M, Yli-Mattila T, Parikka P, Rizzo A, Peltonen K (2004) Food Addit Contam 21:794

    Article  CAS  Google Scholar 

  5. Pressman BC, Harris EJ, Jagger WS, Johnson IH (1967) Proc Nat Acad Sci 58:1949

    Article  CAS  Google Scholar 

  6. Makrlík E, Vaňura P (2006) Monatsh Chem 137:157

    Article  Google Scholar 

  7. Makrlík E, Vaňura P, Selucký P (2008) Monatsh Chem 139:597

    Article  Google Scholar 

  8. Makrlík E, Dybal J, Vaňura P (2009) Monatsh Chem 140:251

    Article  Google Scholar 

  9. Makrlík E, Dybal J, Vaňura P (2009) Monatsh Chem 140:1289

    Article  Google Scholar 

  10. Makrlík E, Dybal J, Vaňura P (2010) Monatsh Chem 141:1191

    Article  Google Scholar 

  11. Dybal J, Makrlík E, Vaňura P (2010) Monatsh Chem 141:15

    Article  CAS  Google Scholar 

  12. Dybal J, Makrlík E, Vaňura P (2011) Monatsh Chem 142:137

    Article  Google Scholar 

  13. Makrlík E, Vaňura P (1985) Talanta 32:423

    Article  Google Scholar 

  14. Makrlík E, Vaňura P, Selucký P (2009) J Solut Chem 38:1129

    Article  Google Scholar 

  15. Makrlík E, Vaňura P, Selucký P (2010) J Solut Chem 39:692

    Article  Google Scholar 

  16. Makrlík E, Vaňura P, Selucký P (2010) Acta Chim Slov 57:922

    Google Scholar 

  17. Makrlík E, Vaňura P (2009) Z Phys Chem 223:247

    Article  Google Scholar 

  18. Makrlík E, Vaňura P, Selucký P (2009) Z Phys Chem 223:253

    Article  Google Scholar 

  19. Makrlík E, Vaňura P, Sedláková Z (2009) J Radioanal Nucl Chem 280:607

    Article  Google Scholar 

  20. Makrlík E, Vaňura P, Selucký P (2010) J Radioanal Nucl Chem 283:571

    Article  Google Scholar 

  21. Makrlík E, Vaňura P, Selucký P (2010) J Radioanal Nucl Chem 284:137

    Article  Google Scholar 

  22. Romanovskiy VN, Smirnov IV, Babain VA, Todd TA, Herbst RS, Law JD, Brewer KN (2001) Solvent Extr Ion Exch 19:1

    Article  CAS  Google Scholar 

  23. Law JD, Herbst RS, Todd TA, Romanovskiy VN, Babain VA, Esimantovskiy VM, Smirnov IV, Zaitsev BN (2001) Solvent Extr Ion Exch 19:23

    Article  CAS  Google Scholar 

  24. Makrlík E, Božek F (1998) Polish J Chem 72:949

    Google Scholar 

  25. Makrlík E, Vaňura P (2010) J Radioanal Nucl Chem 285:683

    Article  Google Scholar 

  26. Makrlík E, Hálová J, Kyrš M (1984) Collect Czech Chem Commun 49:39

    Article  Google Scholar 

  27. Makrlík E, Vaňura P (1996) J Radioanal Nucl Chem 214:339

    Article  Google Scholar 

  28. Makrlík E, Vaňura P (1998) ACH-Models Chem 135:213

    Google Scholar 

  29. Daňková M, Makrlík E, Vaňura P (1997) J Radioanal Nucl Chem 221:251

    Article  Google Scholar 

  30. Makrlík E, Vaňura P, Daňková M (1999) J Radioanal Nucl Chem 240:579

    Article  Google Scholar 

  31. Makrlík E, Selucký P, Vaňura P (2012) Unpublished results

  32. Lee C, Yang W, Parr RG (1988) Phys Rev B 37:785

    Article  CAS  Google Scholar 

  33. Becke AD (1993) J Chem Phys 98:5648

    Article  CAS  Google Scholar 

  34. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery Jr JA, Vreven T, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox JE, Hratchian HP, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong MW, Gonzalez C, Pople JA (2004) Gaussian 03, Revision C. 02. Gaussian, Inc, Wallingford, CT

  35. Kříž J, Dybal J, Makrlík E (2006) Biopolymers 82:536

    Article  Google Scholar 

  36. Kříž J, Dybal J, Makrlík E, Vaňura P, Lang J (2007) Supramol Chem 19:419

    Article  Google Scholar 

  37. Kříž J, Dybal J, Makrlík E, Vaňura P (2008) Supramol Chem 20:387

    Article  Google Scholar 

  38. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2008) Supramol Chem 20:487

    Article  Google Scholar 

  39. Kříž J, Dybal J, Makrlík E, Budka J (2008) J Phys Chem A 112:10236

    Article  Google Scholar 

  40. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2009) J Phys Chem A 113:5896

    Article  Google Scholar 

  41. Kříž J, Toman P, Makrlík E, Budka J, Shukla R, Rathore R (2010) J Phys Chem A 114:5327

    Article  Google Scholar 

  42. Kříž J, Dybal J, Makrlík E, Vaňura P, Moyer BA (2011) J Phys Chem B 115:7578

    Article  Google Scholar 

  43. Boys SF, Bernardi F (1970) Mol Phys 19:553

    Article  CAS  Google Scholar 

  44. van Duijneveldt FB, van Duijneveldt-van de Rijdt JGCM, van Lenthe JH (1994) Chem Rev 94:1873

  45. Hobza P, Šponer J (1999) Chem Rev 99:3247

    Article  CAS  Google Scholar 

  46. Hawthorne MF, Young DC, Andrews TD, Howe DV, Pilling RL, Pitts AD, Reintjes M, Warren LF, Wegner PA (1968) J Am Chem Soc 90:879

    Article  CAS  Google Scholar 

  47. Makrlík E (1992) Collect Czech Chem Commun 57:289

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Grant Agency of the Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114, “Environmental Aspects of Sustainable Development of Society” by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307), and by the Czech Science Foundation (Project P 205/10/2280).

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Petr Toman

  3. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Petr Toman
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Toman, P. & Vaňura, P. Complexation of Pb2+ with beauvericin: an experimental and theoretical study. Monatsh Chem 144, 1461–1465 (2013). https://doi.org/10.1007/s00706-013-1054-z

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  • DOI: https://doi.org/10.1007/s00706-013-1054-z

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