Skip to main content
SpringerLink
Log in

Potentiometric determination of stability constants and thermodynamic data for dimethyltin(IV) dichloride complexes with iminobis(methylphosphonic acid) in water and dioxane–water mixtures

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

The interaction of dimethyltin(IV) (DMT) with iminobis(methylphosphonic acid) (IDP) was investigated at 25 °C and ionic strength 0.1 mol dm−3 NaCl using the potentiometric technique. The formation constants of the complexes formed in solution were calculated using the non-linear least-squares program MINIQUAD-75. The stoichiometry and stability constants for the complexes formed are reported. The results showed the formation of 110, 111, 112, 11-1, and 11-2 for DMT–IDP complexes. The concentration distribution of the various complex species was evaluated. The effect of dioxane as a solvent on the hydrolysis of DMT and both the protonation and the formation constants of DMT complexes with IDP was discussed. The thermodynamic parameters ΔH° and ΔS° were calculated from the temperature dependence of the equilibrium constants. The effect of ionic strength on the hydrolysis of DMT, the protonation of IDP, and the formation constants of DMT–IDP complexes was also discussed.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Kiss T (1990) In: Burger K (ed) Biocoordination chemistry. Ellis Horwood, Chichester, p 56 (and references cited therein)

    Google Scholar 

  2. Monsato A (1985) Round up herbicides by Monsato. Monsato, St. Louis, p 9

    Google Scholar 

  3. Lejczak B, Kafarski P, Zygmunt J (1989) Biochemistry 28:3549

    Article  CAS  Google Scholar 

  4. Dhansay MA, Linder PW (1993) J Coord Chem 28:133

    Article  CAS  Google Scholar 

  5. El-Sherif AA (2011) J Coord Chem 64:1240

    Article  CAS  Google Scholar 

  6. El-Sherif AA, Shoukry MM (2006) J Main Group Metal Chem 29:189

    CAS  Google Scholar 

  7. Gilen M (2002) Appl Organomet Chem 16:481

    Article  Google Scholar 

  8. Szorcsik A, Nagy L, Deák A, Scopelliti M, Fekete ZA, Császár Á, Pellerito C, Pellerito L (2004) J Organomet Chem 689:2762

    Article  CAS  Google Scholar 

  9. Ma C, Li J, Zhang R, Wang D (2005) Inorg Chim Acta 358:4575

    Article  CAS  Google Scholar 

  10. Pellerito L, Nagy L (2002) Coord Chem Rev 224:111

    Article  CAS  Google Scholar 

  11. Quevauviller P, Ritsema R, Morabit R, Dirkx WMR (1994) Appl Organomet Chem 8:541

    Article  CAS  Google Scholar 

  12. Duboy SK, Roy U (2003) Appl Organomet Chem 17:3

    Article  Google Scholar 

  13. Álvarez-Boo P, Casas JS, Couce MD, Farto R, Moreira VF, Freijanes E, Sordo J, López EV (2006) J Organomet Chem 691:45

    Article  Google Scholar 

  14. Álvarez-Boo P, Casas JS, Castineiras A, Couce MD, Freijanes E, Novoa E, Sordo J (2003) Appl Organomet Chem 17:725

    Article  Google Scholar 

  15. Narayanan V, Nasr M, Paull KD (1990) In: Gielen M (ed) Tin-based anti-tumor drugs. Springer, Berlin, p 201

    Chapter  Google Scholar 

  16. Gielen M (1996) Coord Chem Rev 151:41

    CAS  Google Scholar 

  17. El-Sherif AA (2012) J Solut Chem 41:1522

    Article  CAS  Google Scholar 

  18. El-Sherif AA, Shoukry MM (2005) J Coord Chem 58:1401

    Article  CAS  Google Scholar 

  19. El-Sherif AA, Shoukry MM (2006) J Coord Chem 59:1541

    Article  CAS  Google Scholar 

  20. El-Sherif AA, Shoukry MM (2007) Spectrochim Acta A 66:691

    Article  Google Scholar 

  21. Jeragh BJ, Al-Wahaib D, El-Sherif AA, El-Dissouky A (2007) J Chem Eng Data 52:1609

    Article  CAS  Google Scholar 

  22. Al-Kandary A, Mandani FMA, Al-Jimaz AS, El-Sherif AA, Shoukry MM (2007) J Solut Chem 36:247

    Article  CAS  Google Scholar 

  23. Al-Awadi NA, Shuaib NM, Abbas A, El-Sherif AA, El-Dissouky A, Al-Saleh E (2008) Bioinorg Chem Appl (article ID 479897)

  24. El-Sherif AA (2010) J Solut Chem 39:131

    Article  CAS  Google Scholar 

  25. El-Sherif AA (2012) J Solut Chem 41:249

    Article  CAS  Google Scholar 

  26. Sanna D, Bodi I, Bouhsina S, Micera G, Kiss T (1999) J Chem Soc Dalton Trans 3275

  27. Kurzak B, Kamecka A, Kurzak K, Jezierska J, Kafarski P (2000) Polyhedron 19:2083

    Article  CAS  Google Scholar 

  28. Tobias RS, Yasuda M (1964) Can J Chem 42:781

    Article  CAS  Google Scholar 

  29. Nath M, Jairath R, George E, Xuequing S, Kumar A (2005) Spectrochim Acta A 61:77

    Article  Google Scholar 

  30. Arena G, Purrello R, Rizzarelli E, Gianguzza A, Pellerito L (1989) J Chem Soc Dalton Trans 773

  31. Natsume T, Aizawa S-I, Hatano K, Funahashi H (1994) J Chem Soc Dalton Trans 2749

  32. Gamsjäger H, Gajda T, Sangster J, Saxena SK, Voigt W (2013) Chem Thermodyn 12:439

    Google Scholar 

  33. Kramer-Schnabel U, Linder PW (1991) Inorg Chem 30:1248

    Article  CAS  Google Scholar 

  34. Rees DC (1980) J Mol Biol 141:323

    Article  CAS  Google Scholar 

  35. Rogersa NK, Mooreb GR, Sternberga MJE (1985) J Mol Biol 182:613

    Article  Google Scholar 

  36. Akerlof G, Short OA (1953) J Am Chem Soc 75:6357

    Google Scholar 

  37. Jameson RF, Wilson MF (1972) J Chem Soc Dalton Trans 2507

  38. Mohamed MMA, Shehata MR, Shoukry MM (2001) J Coord Chem 53:125

    Article  CAS  Google Scholar 

  39. Rorabacher DB, MacKellar WJ, Shu FR, Bonavita SM (2011) Anal Chem 43:561

    Article  Google Scholar 

  40. Sharma RK, Jha NS, Sindhwani SK (1984) Thermochim Acta 156:267

    Article  Google Scholar 

  41. Shoukry MM, Shoukry EM, El-Medani SM (1995) Monatsh Chem 126:909

    Article  CAS  Google Scholar 

  42. Sigel H (1989) Pure Appl Chem 61:923

    Article  CAS  Google Scholar 

  43. Brönsted JN (1922) J Am Chem Soc 44:877

    Article  Google Scholar 

  44. Ciavatta L (1980) Ann Chim (Rome) 70:551

    CAS  Google Scholar 

  45. Ciavatta L (1990) Ann Chim (Rome) 80:255

    CAS  Google Scholar 

  46. Guggenheim EA, Turgeon JC (1955) Trans Faraday Soc 51:747

    Article  CAS  Google Scholar 

  47. Gamsjäger H, Lorimer JW, Scharlin P, Shaw DG (2008) Pure Appl Chem 80:233

    Article  Google Scholar 

  48. De Stefano C, Foti C, Sammartano S, Gianguzza A, Rigano C (1994) Ann Chim (Rome) 84:159

    Google Scholar 

  49. Bretti C, Foti C, Porcino N, Sammartano S (2006) J Solut Chem 35:1401

    Article  CAS  Google Scholar 

  50. Van Uitert GL, Hass CG (1971) J Am Chem Soc 75:451

    Article  Google Scholar 

  51. Motekaitis RJ, Martell AE, Nelson DA (1984) Inorg Chem 23:275

    Article  CAS  Google Scholar 

  52. Serjeant EP (1984) Potentiometry and potentiometric titrations. Wiley, New York

    Google Scholar 

  53. Hay RW, Morris PJ (1976) In: Sigel H (ed) Metal ions in biological systems, vol 5. Marcel Dekker, New York, p 73

    Google Scholar 

  54. Gans P, Sabatini A, Vacca A (1976) Inorg Chim Acta 18:237

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Pharmacy, King Abd Al-Aziz University, Jeddah, 21589, Kingdom of Saudi Arabia

    M. Aljahdali

  2. Dipartimento di Scienze Chimiche, Università di Messina, Viale F. Stagno d’Alcontres 31, 98166, Messina, Italy

    Claudia Foti

  3. Department of Chemistry, Faculty of Science, Cairo University, Cairo, Egypt

    Ahmed A. El-Sherif & Ahmed A. Soliman

  4. Department of Chemistry, Faculty of Arts and Science, Northern Borders University, Rafha City, Kingdom of Saudi Arabia

    Ahmed A. El-Sherif

  5. Department of Sciences and Mathematics, New-Valley Faculty of Education, Assiut University, Assiut, Egypt

    Mahmoud M. A. Mohamed

  6. Department of Chemistry, Faculty of Pharmacy, King Saud University, Riyadh, Kingdom of Saudi Arabia

    Obaid S. Al Ruqi

Authors
  1. M. Aljahdali
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Claudia Foti
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ahmed A. El-Sherif
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mahmoud M. A. Mohamed
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ahmed A. Soliman
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Obaid S. Al Ruqi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ahmed A. El-Sherif.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aljahdali, M., Foti, C., El-Sherif, A.A. et al. Potentiometric determination of stability constants and thermodynamic data for dimethyltin(IV) dichloride complexes with iminobis(methylphosphonic acid) in water and dioxane–water mixtures. Monatsh Chem 144, 1467–1480 (2013). https://doi.org/10.1007/s00706-013-1023-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-013-1023-6

Keywords

Search

Navigation