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Spectrophotometric Determination of Equilibrium Constants of Dimethyl and Diethyltin(IV) Dichloride with 5,10,15,20-Tetrakis(4-trimethyl-ammonio-phenyl)-prophine Tetratosylate

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Abstract

The formation constant of dimethyl and diethyltin(IV) dichloride hydrolytic species and their complexation reactions with 5,10,15,20-tetrakis(4-trimethyl-ammonio-phenyl)-prophine tetratosylate (TTMAPP) were evaluated using potentiometric and spectrophotometric methods. 1H NMR spectra of dimethyl and diethyltin(IV) at different pHs have an octahedral structure in low pHs and a distorted trigonal bipyramidal structural arrangement at higher pH values. The compositions of the formed complexes were determined, and it was shown that they form a single mononuclear 1:1 species with the ligand. The results indicate that the formation constants are in the order Me2Sn(IV)–TTMAPP > Et2Sn(IV)–TTMAPP.

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  1. Chemistry Department, Shahid Beheshti University, G. C. Evin, Tehran, Iran

    Fatemeh Jaberi & Farrokh Gharib

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  1. Fatemeh Jaberi
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Jaberi, F., Gharib, F. Spectrophotometric Determination of Equilibrium Constants of Dimethyl and Diethyltin(IV) Dichloride with 5,10,15,20-Tetrakis(4-trimethyl-ammonio-phenyl)-prophine Tetratosylate. J Solution Chem 44, 34–44 (2015). https://doi.org/10.1007/s10953-015-0290-8

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