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Fabrication of an Er3+ PVC membrane sensor based on oxalic acid bis[2-[(phenylamino)carbonyl]hydrazide]

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Abstract

A highly selective and sensitive Er3+ sensor was constructed with a polyvinyl chloride matrix membrane containing oxalic acid bis[2-[(phenylamino)carbonyl]hydrazide] as a neutral carrier, sodium tetraphenyl borate as a cationic additive and nitrobenzene as a plasticizing solvent mediator. The proposed sensor exhibits linear potential response with a Nernstian slope of 19.7 ± 0.4 mV decade−1 of activity in the Er3+ concentration range of 1.0 × 10−6 to 1.0 × 10−2 mol dm−3 in the pH range of 2.7–10.2. It has a very short response time (<10 s), a detection limit of 5.8 × 10−7 mol dm−3 and good selectivity relative to a wide variety of other metal ions including common alkali, alkaline earth, heavy and transition metal ions. The sensor can be used for at least 2 months without any considerable divergence in potentials. The proposed sensor was successfully applied as an indicator electrode for the potentiometric titration of 1.0 × 10−4 mol dm−3 of Er3+ ions with a 1.0 × 10−2 mol dm−3 EDTA. It was also used in the indirect determination of F− ions in some mouthwash solutions.

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Acknowledgments

The authors acknowledge the kind financial support provided by the Research Council of Quchan Islamic Azad University and Sama Institution of Quchan branch for the preparation of this study.

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Authors and Affiliations

  1. Department of Applied Chemistry, Quchan Branch, Islamic Azad University, Quchan, Iran

    Hassan A. Zamani

  2. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran

    Mohammad R. Ganjali

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  1. Hassan A. Zamani
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  2. Mohammad R. Ganjali
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Correspondence to Hassan A. Zamani.

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Zamani, H.A., Ganjali, M.R. Fabrication of an Er3+ PVC membrane sensor based on oxalic acid bis[2-[(phenylamino)carbonyl]hydrazide]. Monatsh Chem 141, 1183–1189 (2010). https://doi.org/10.1007/s00706-010-0394-1

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  • DOI: https://doi.org/10.1007/s00706-010-0394-1

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