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Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion

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Abstract

An ion-selective electrode (ISE) based on a plasticized polyvinyl chloride membrane chemically doped with tetradecylammonium octahydrotriborate ([(С10H21)4N+]\([{{{\text{B}}}_{{\text{3}}}}{\text{H}}_{8}^{ - }]\)) has been developed. It is shown that the electrode has a reversible potentiometric response with respect to the octahydrotriborate anion in the presence of a number of other inorganic anions. The influence of the concentration of the electrode-active material and the nature of the plasticizer in the membrane phase on the electrochemical characteristics of the fabricated sensor have been studied. The optimal composition of the ion-sensitive membrane has been found. It has been found that the developed sensor provides a wide range of detectable concentrations of \({{{\text{B}}}_{{\text{3}}}}{\text{H}}_{8}^{ - }\) (1 × 10–7…1 × 10–2) and a low detection limit (10–7.3 M). The new ISE can be recommended for direct potentiometric detection of free octahydrotriborate anions in technological aqueous solutions.

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Center for Collective Use of the Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences and the Council for Grants of the President of the Russian Federation (project MK-207.2022.1.3).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Kopytin, E. S. Turyshev, A. S. Kubasov, K. Yu. Zhizhin, L. K. Shpigun & N. T. Kuznetsov

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    M. Sh. Madraimov

Authors
  1. A. V. Kopytin
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  2. E. S. Turyshev
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  3. M. Sh. Madraimov
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  4. A. S. Kubasov
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  5. K. Yu. Zhizhin
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  6. L. K. Shpigun
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  7. N. T. Kuznetsov
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Corresponding author

Correspondence to E. S. Turyshev.

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Translated by V. Avdeeva

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Kopytin, A.V., Turyshev, E.S., Madraimov, M.S. et al. Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion. Russ. J. Inorg. Chem. 68, 6–12 (2023). https://doi.org/10.1134/S0036023622700103

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  • DOI: https://doi.org/10.1134/S0036023622700103

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