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The Behavior of 3,3-Diphenylindan-1,2-dione Towards Alkyl Phosphites

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Summary.

The reaction of 3,3-diphenylindan-1,2-dione with trimethyl phosphite in dry benzene at room temperature for about 15 h led to the formation of a mixture containing dimethyl (3,3-diphenyl-2-methoxy-1-indenyl)phosphate and dimethyl (3,3-diphenyl-1H-2-oxo-1-indanyl)phosphate, whereas with triisopropyl phosphite, diisopropyl (3,3-diphenyl-2-isopropoxy-1-indenyl)phosphate is the only product. Treatment of the dione with dialkyl phosphites under different experimental conditions gave dialkyl (3,3-diphenyl-1-hydroxy-2-oxo-1-indanyl)phosphates. Reaction mechanisms are presented which account for the experimental results. Structural assignments of the new compounds are based on the spectroscopic evidences and two examples were elucidated by X-ray crystallography.

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Authors and Affiliations

  1. National Research Centre, Dokki, Cairo, Egypt

    Fayez H. Osman & Fatma A. El-Samahy

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  1. Fayez H. Osman
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  2. Fatma A. El-Samahy
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Correspondence to Fayez H. Osman.

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Osman, F., El-Samahy, F. The Behavior of 3,3-Diphenylindan-1,2-dione Towards Alkyl Phosphites. Monatsh. Chem. 138, 973–978 (2007). https://doi.org/10.1007/s00706-007-0692-4

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  • DOI: https://doi.org/10.1007/s00706-007-0692-4

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