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PVDF-triggered multicolor fluorine-doped graphene quantum dots for water detection and anti-counterfeiting

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Abstract

Fluorescent fluorine-doped graphene quantum dots (F-GQDs) have been synthesized via the hydrothermal method using long-chain polymer polyvinylidene fluoride (PVDF) as the precursor. Due to the unique molecular structure of PVDF, a possible synthesis process of F-GQDs has been put forward. F-GQDs have adjustable emission wavelength by simply adjusting the concentration of the solution. As the concentration increases, the emission wavelength of F-GQDs gradually red shifts from 455 nm (blue) to 551 nm (yellow-green). In addition, F-GQDs also exhibit a sensitive fluorescence response to water content in organic solvents, and the ultralow detections limit are 0.056% in ethanol and 0.124% in DMF. Besides, due to strong UV absorption capacity, a photothermal film is fabricated by embedding F-GQDs in PDMS. The temperature of F-GQDs/PDMS polymer film can reach 33.4 oC under simulated sunlight, while the maximum temperature of blank PDMS film only reach 29.4 oC. Based on this phenomenon, a new type of anti-counterfeiting device is designed by combining F-GQDs/PDMS film with temperature change ink.

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Funding

This work was supported by projects from National Natural Science Foundation of China under Grant (Nos. 11704204, 61604084, and 51802337), the State Key Laboratory of ASIC & System (Grant No. 2020KF007), and K. C. Wong Magna Fund in Ningbo University. The authors declare no competing financial interest.

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Authors and Affiliations

  1. Department of Microelectronic Science and Engineering, School of Physical Science and Technology, Ningbo University, Ningbo, 315211, People’s Republic of China

    Changxing Wang, Da Chen, Siyuan Tang, Yongsheng Yang, Xiameng Li & Feng Xie

  2. School of Microelectronics, Shandong University, Jinan, 250100, People’s Republic of China

    Qinglei Guo

  3. State Key Laboratory of ASIC and Systems, Fudan University, Shanghai, 200433, People’s Republic of China

    Qinglei Guo

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  1. Changxing Wang
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  2. Da Chen
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Wang, C., Chen, D., Tang, S. et al. PVDF-triggered multicolor fluorine-doped graphene quantum dots for water detection and anti-counterfeiting. Microchim Acta 189, 6 (2022). https://doi.org/10.1007/s00604-021-05108-1

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