Abstract
A series of devices with the structure of ITO\poly(methoxy-5-(2′-ethylhexyloxy)-1,4-phyenylenevinylene) (MEH-PPV):fullerene (C60, 0 ~ 60 wt%)\Al were fabricated and measured. It is found that the device with 20 wt% C60 concentration exhibited an optimized performance for the role of piezoresistive sensing. The piezoresistive coefficient showed 0.12 ~ 0.32 Pa−1 in the pressure range of 0 ~ 396 kPa. We measured the 20 wt% C60-doped MEH-PPV film using a nanoindentation tester with a flat punch and obtained its Young’s modulus at equilibrium state (E0) to be ~ 170 MPa. The present work shows that a proper amount of fullerene doped in MEH-PPV film would improve the conductivity of the film, thus leading an enhanced working current density, increasing the current signal for sensing the applied stress, while the necessary elasticity or resilience of the films are maintained. The device performance is optimized through changing the C60 doping concentration to be 20 wt%, approaching a good balance of elasticity and conductivity. Therefore, the device shows a better general performance than the undoped device, exhibiting a better prospect for tactile sensing.
Similar content being viewed by others
References
Alegret N, Dominguez-Alfaro A, Salsamendi M, Gomez IJ, Calvo J, Mecerreyes D, Prato M (2017) Effect of the fullerene in the properties of thin PEDOT/C60 films obtained by co-electrodeposition. Inorg Chim Acta 468:239–244
Aruna P, Suresh K, Joseph CM (2015) Effect of fullerene doping on the electrical properties of P3HT/PCBM layers. Mat Sci Semicon Proc 36:7–12
Bai Y, Dong Q, Shao Y, Deng Y, Wang Q, Shen L, Wang D, Wei W, Huang J (2016) Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene. Nat Commun 7(1):12806
Bhardwaj J, Vishnoi R, Sharma GD, Asokan K, Singhal R (2020) Mapping the local structure of fullerene C60 and Cu–C60 nanocomposite thin films by gamma rays irradiation. Mater Chem Phys 252:123192
Cao XA, Jiang ZY, Zhang YQ (2011) Organic thin film structures for high-sensitivity imaging of contact stress distributions. Org Electron 12(2):306–311
Dai W, Zhang B, Kang Y, Chen H, Zhong G, Li Y (2013) The stress-affected carrier injection and transport in organic semiconductor devices. J Phys D Appl Phys 46(38):385103
Doerner MF, Nix WD (1986) A method for interpreting the data from depth-sensing indentation instruments. J Mater Res 1(4):601–609
Gong S, Schwalb W, Wang Y, Chen Y, Tang Y, Si J, Shirinzadeh B, Cheng W (2014) A wearable and highly sensitive pressure sensor with ultrathin gold nanowires. Nat Commun 5(1):1–8
He R, Yang P (2006) Giant piezoresistance effect in silicon nanowires. Nat Nanotechnol 1(1):42–46
Hou W, Gao L, Tian Y, Yan W, Hou Y, Li J, Zhong G (2017) Stress-induced variation of MDMO-PPV film thickness and resistance. Synthetic Met 226:113–118
Kim J, Lee M, Shim HJ, Ghaffari R, Cho HR, Son D, Jung YH, Soh M, Choi C, Jung S, Chu K, Jeon D, Lee S, Kim JH, Choi SH, Hyeon T, Kim D (2014) Stretchable silicon nanoribbon electronics for skin prosthesis. Nat Commun 5(1):1–11
Kodzasa T, Nobeshima D, Kuribara K, Uemura S, Yoshida M (2017) Fabrication and performance of pressure-sensing device consisting of electret film and organic semiconductor. Jpn J Appl Phys 56(4S):04CL09
Li Y, Cheng XY, Leung MY, Tsang J, Yuen TXM, MCW. (2005) A flexible strain sensor from polypyrrole-coated fabrics. Synthetic Met 155(1):89–94
Li J, Li J, Hou Y, Hou Y, Wang Y, Wang Y, Ye F, Ye F, Zhong G, Zhong G (2019) The piezoresistance of a device with polyphenylenevinylene derivative PSS-PPV film. Microsyst Technol 25(2):423–430
Liao S, Jhuo H, Cheng Y, Chen S (2013) Fullerene derivative-doped zinc oxide nanofilm as the cathode of inverted polymer solar cells with low-bandgap polymer (PTB7-Th) for high performance. Adv Mater 25(34):4766–4771
Lipomi DJ, Vosgueritchian M, Tee BC, Hellstrom SL, Lee JA, Fox CH, Bao Z (2011) Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes. Nat Nanotechnol 6(12):788–792
Lötters JC, Olthuis W, Veltink PH, Bergveld P (1997) The mechanical properties of the rubber elastic polymer polydimethylsiloxane for sensor applications. J Micromech Microeng 7(3):145–147
Lu N, Kim D (2014) Flexible and stretchable electronics paving the way for soft robotics. Soft Robot 1(1):53–62
Mansuroglu D, Uzun-Kaymak IU (2017) Enhancement of electrical conductivity of plasma polymerized fluorene-type thin film under iodine and chlorine dopants. Thin Solid Films 636:773–778
Milne JS, Rowe ACH, Arscott S, Renner C (2010) Giant Piezoresistance Effects in Silicon Nanowires and Microwires. PHYS REV LETT 105(22):226802
Mirza F, Sahasrabuddhe RR, Baptist JR, Wijesundara MBJ, Lee WH, Popa DO (2016) Piezoresistive pressure sensor array for robotic skin. In: D. Popa and M. Wijesundara (Eds) Proceedings of SPIE, pp. 98590K-98590K-12, SPIE, Baltimore, Maryland, United States
Niu L, Guan Y (2009) Fullerene-doped hole transport NPB layer in organic light-emitting devices. Acta Phys Sin-Ch Ed 58(7):4931–4935
Oliver WC, Pharr GM (1992) An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J Mater Res 7(6):1564–1583
Pope M, Swenberg CE (1999) Electronic processes in organic crystals and polymers. Oxford University Press, Oxford
Schwartz G, Tee BCK, Mei J, Appleton AL, Kim DH, Wang H, Bao Z (2013) Flexible polymer transistors with high pressure sensitivity for application in electronic skin and health monitoring. Nat Commun 4(1):1–8
Smilowitz L, McBranch D, Klimov V, Grigorova M, Robinson JM, Weyer BJ, Koskelo A, Mattes BR, Wang H, Wudl F (1997) Fullerene doped glasses as solid state optical limiters. Synthetic Met 84(1–3):931–932
Someya T, Kato Y, Sekitani T, Iba S, Noguchi Y, Murase Y, Kawaguchi H, Sakurai T (2005) Conformable, flexible, large-area networks of pressure and thermal sensors with organic transistor active matrixes. Proc Natl Acad Sci 102(35):12321–12325
Sun X, Sun J, Li T, Zheng S, Wang C, Tan W, Zhang J, Liu C, Ma T, Qi Z, Liu C, Xue N (2019) Flexible tactile electronic skin sensor with 3D force detection based on porous CNTs/PDMS nanocomposites. Nano-Micro Lett 11(1):1–14
Vaez TH, Hirata A (2011) Deposition of amorphous carbon films from C60 fullerene sublimated in electron beam excited plasma. Diam Relat Mater 20(7):1036–1041
Yuan Y, Grozea D, Lu ZH (2005) Fullerene-doped hole transport molecular films for organic light-emitting diodes. Appl Phys Lett 86(14):143509
Zhong GY, Zhang YQ, Cao XA (2009) Conjugated polymer films for piezoresistive stress sensing. IEEE Electr Device L 30(11):1137–1139
Zhong GY, Yan WQ, Li J, Tian YM (2019a) Determining Young’s modulus of MEH-PPV film by fitting the unloading curve. Microsyst Technol 25(4):1467–1474
Zhong W, Ding X, Li W, Shen C, Yadav A, Chen Y, Bao M, Jiang H, Wang D (2019b) Facile fabrication of conductive graphene/polyurethane foam composite and its application on flexible piezo-resistive sensors. Polymers-Basel 11(8):1289
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China under Grant 51373036 (Gaoyu Zhong) and the National Science Foundation for Young Scientists of China under Grant 61704107 (Yijie Xia).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Xia, Y., Wu, L., Li, S. et al. The piezoresistive performances of the devices with fullerene-doped MEH-PPV films. Microsyst Technol 27, 2661–2670 (2021). https://doi.org/10.1007/s00542-020-05039-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00542-020-05039-6