Skip to main content
Log in

Chromite alteration processes within Vourinos ophiolite

  • Original Paper
  • Published:
International Journal of Earth Sciences Aims and scope Submit manuscript

Abstract

The renewed interest in chromite ore deposits is directly related to the increase in Cr price ruled by international market trends. Chromite, an accessory mineral in peridotites, is considered to be a petrogenetic indicator because its composition reflects the degree of partial melting that the mantle experienced while producing the chromium spinel-bearing rock (Burkhard in Geochim Cosmochim Acta 57:1297–1306, 1993). However, the understanding of chromite alteration and metamorphic modification is still controversial (e.g. Evans and Frost in Geochim Cosmochim Acta 39:959–972, 1975; Burkhard in Geochim Cosmochim Acta 57:1297–1306, 1993; Oze et al. in Am J Sci 304:67–101, 2004). Metamorphic alteration leads to major changes in chromite chemistry and to the growth of secondary phases such as ferritchromite and chlorite. In this study, we investigate the Vourinos complex chromitites (from the mines of Rizo, Aetoraches, Xerolivado and Potamia) with respect to textural and chemical analyses in order to highlight the most important trend of alteration related to chromite transformation. The present study has been partially funded by the Aliakmon project in collaboration between the Public Power Corporation of Greece and Institute of Geology and Mineral Exploration of Kozani.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  • Auzende AL, Guillot G, Devouard B, Baronnet A (2006) Behaviour of serpentinites in convergent context: microstructural evidences. Eur J Mineral 18:21–33

    Google Scholar 

  • Bach W, Paulick H, Garrido CJ, Ildefonse B, Meurer WP, Humphris SE (2006) Unravelling the sequence of serpentinization reactions: petrography, mineral chemistry, and petrophysics of serpentinites from MAR 15°N (ODP Leg 209, Site 1274). Geoph Res Lett 33:L13306. doi:10.1029/2006GL025681

  • Barnes SJ (2000) Chromite in komatiites, II modification during Greenschist to mid-amphibolite facies metamorphism. J Petrol 41:387–409

    Article  Google Scholar 

  • Bortolotti V, Chiari M, Marcucci M, Marroni M, Pandolfi L, Principi G, Saccani E (2004) Comparison among the Albanian and Greek ophiolites; in search of constraints for the evolution of the Mesozoic Tethys Ocean. Ofioliti 29(14):19–35

    Google Scholar 

  • Burkhard DJM (1993) Accessory chromium spinels: their coexistence and alteration in serpentinites. Geochim Cosmochim Acta 57:1297–1306

    Article  Google Scholar 

  • Christofides G, Thimiatis G, Koroneos A, Sklavounos SNS, Eleftheriadis G (1994) Mineralogy and chemistry of Cr-chlorites associated with chromites from vavdos and vasilika ophiolite complexes (Chalikidiki, Macedonia, N. Greece). Chemie der Erde 54:151–166

    Google Scholar 

  • Dick HJB, Bullen T (1984) Chromian spinel as a petrogenetic indicator in abysal and alpine-type peridotites and spatiallly associated lavas. Contrib Mineral Petrol 86:54–76

    Article  Google Scholar 

  • Dilek Y, Shallo M, Furnes H (2005) Rift-drift, seafloor spreading, and subduction tectonics of Albanian ophiolites. Int Geol Rev 47:147–176

    Article  Google Scholar 

  • Economou-Eliopoulos M (1996) Platinum-group element distribution in chromite ores from ophiolite complexes: implications for their exploration. Ore Geol Rev 11:363–381

    Article  Google Scholar 

  • Economou-Eliopoulos M, Vacondis I (1995) Geochemistry of chromitites and host rocks from the pindos ophiolite complex, northwestern Greece. Chem Geol 122:99–108

    Article  Google Scholar 

  • Evans B, Frost RB (1975) Chrome spinel in progressive metamorphism: a preliminary analysis. Geochim et Cosmochim Acta 39:959–972

    Article  Google Scholar 

  • Filippidis A (1997) Chemical variation of chromite in the central sector of xerolivado chrome mine of Vourinos, Western Macedonia, Greece. NJ Miner Mn 8:354–370

    Google Scholar 

  • Frost BR, Beard JS (2007) On silica activity and serpentinization. J Petrol 7:1351–1368

    Article  Google Scholar 

  • Graham J (1978) Manganochromite, palladium, antimonide, and some unusal mineral associations at the Nairne pyrite deposit, South Australia. Am Mineral 63:1166–1174

    Google Scholar 

  • Grivas E, Rassios A, Konstantopoulou G, Vacondios I, Vrahatis G (1993) Drilling for “blind” podiform chrome orebodies at Voidolakkos in the Vourinos ophiolite complex Greece. Econ Geol 88(2):461–468

    Article  Google Scholar 

  • Hajialioghli R, Moazzen M, Droop GTR, Oberhansli R, Bousquet R, Jhngri A, Ziemann M (2007) Serpentine polymorphs and P-T evolution of metaperidotites and serpentinite in the Takab area, NW Iran. Mineral Mag 71:203–222

    Google Scholar 

  • Koneva AA (1997) Cr-V-manganospinels in metamorphic rocks, Lake Baikal, Russia. Min Mag 61:145–148

    Article  Google Scholar 

  • Konstantopoulou G (1993) Structural criteria in locating chromite ores: evidence from the Rizo district, Vourinos ophiolite, Greece. Bull Geol Soc Greece 28:381–392

    Google Scholar 

  • Konstantopoulou G, Economou-Eliopoulos M (1991) Distribution of platinum-group elements and gold within the Vourinos chromitite ores, Greece. Econ Geol 86(8):1672–1682

    Article  Google Scholar 

  • Liati A, Gebauer D, Fanning CM (2004) The age of ophiolitic rocks of the Hellenides (Vourinos, Pindos, Crete): first U–Pb ion microprobe (SHRIMP) zircon ages. Chem Gol 207:171–188

    Article  Google Scholar 

  • Margaras S, Vacondios I (1996) Metallogenic map of the Vourinos ophiolite complex (West Macedonia, Greece). IGME, Greece

    Google Scholar 

  • Merlini A, Grieco G, Diella V (2009) Ferritchromite and chromian chlorite formation in mèlange-hosted Kalkan chromitite (Southern Urals, Russia). Am Mineral 94:1459–1467

    Google Scholar 

  • Oze C, Fendorf S, Bird D, Coleman R (2004) Chromium geochemistry in serpentinized ultramafic rocks and serpentine soils from the Franciscan complex of California. Am J Sci 304:67–101

    Article  Google Scholar 

  • Papanikolaou D, Barghathi H, Dabovski C, Dimitriu R, El-Hawat A, Ioane D, Kranis H, Obeidi A, Oaie G, Seghedi A, Zagorchev I (2004) Transect VII; East European Craton, Scythian Platform, Dobrogea, Balkanides, Rhodope Massif, Hellenides, East Mediterranean, Cyrenaica. In: Cavazza, Roure F, Spakman W, Stampfli GM, Ziegler PA (eds) The TRANSMED atlas; the Mediterranean region from crust to mantle; geological and geophysical framework of the Mediterranean and the surrounding areas. Springer, New York

  • Papanikolau D (1997) The tectonostratigraphic terranes of the Hellenides. Final volume of IGCP 276. Ann Geol Pays Hell 37:495–514

    Google Scholar 

  • Paulick H, Bach W, Godard M, De Hoog JCM, Suhr G, Harvey J (2006) Geochemistry of abyssal peridotites (Mid-Atlantic Ridge, 15°20′N, ODP Leg 209): implications for fluid/rock interaction in slow spreading environments. Chem Geol 234:179–210

    Article  Google Scholar 

  • Pawley A (2002) Chlorite stability in mantle peridotite: the reaction clinochlore + enstatite = forsterite + pyrope + H2O. Contr Mineral Petrol 144(4):449–456

    Article  Google Scholar 

  • Rassios AE (2004) A geologist’s guide to West macedonia, Greece. AN.N.GRE, Grevena

  • Rassios AE, Moores EM (2006) Heterogeneous mantle complex, crustal processes, and obduction kinematics in a unified Pindos-Vourinos ophiolitic slab. In: Robertson AHF, Mountrakis D (eds) Tectonic development of the eastern Mediterranean region. Geol Soc Spec Publ 260:237–266

  • Rassios AE, Dilek Y, Kostopoulos D (2008) The northeastern emplacement of the Pindos Basin ophiolites and their response to Pelagonian exhumation tectonics (northern Greece). Geological Society of America, 2008 annual meeting. In: Abstracts with Programs Geological Society of America 40(6):109

  • Roberts S (1988) Ophiolite chromite formation: a marginal basin phenomenon. Econ Geol 83:1034–1036

    Article  Google Scholar 

  • Ross JV, Mercier JCC, Avé Lallemant HG, Carter NL, Zimmerman J (1980) The Vourinos ophiolite complex: the tectonite suite. Tectonophysics 70:63–83

    Article  Google Scholar 

  • Saccani E, Beccaluva L, Coltorti M, Siena F (2004) Petrogenesis and tectono-magmatic significance of the Albanide-Hellenide subpelagonian ophiolites. Ofioliti 29(1):75–93

    Google Scholar 

  • Seyfried WE, Foustoukos DI (2007) Redox evolution and mass transfer during serpentinization: an experimental and theoretical study at 200°C, 500 bar with implications for ultramafic-hosted hydrothermal systems at Mid-Ocean Ridges. Geochim Cosmochim Acta 71:3872–3886

    Article  Google Scholar 

  • Smith AG, Rassios A (2003) The evolution of ideas for the origin and emplacement of the western Hellenic ophiolites. In: Dilek Y (ed) Ophiolite concept and the evolution of geological thought. Spec Paper Geol Soc Am 373:337–350

  • Spangeberg K (1943) Die chromietlagerstatte vom tampadel in zobten. Zeitschr Parkt Geologie 5:13–35

    Google Scholar 

Download references

Acknowledgments

We wish to thank Prof. A. Rassios and all the staff of Aliakmon project and all the students that worked in collaboration between the Public Power Corporation of Greece and Institute of Geology and Mineral Exploration (IGME) of Kozani.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anna Merlini.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Grieco, G., Merlini, A. Chromite alteration processes within Vourinos ophiolite. Int J Earth Sci (Geol Rundsch) 101, 1523–1533 (2012). https://doi.org/10.1007/s00531-011-0693-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00531-011-0693-8

Keywords

Navigation