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Tunable double-stranded inclusion complexes of γ-cyclodextrin threaded onto non-modified poly(ethylene glycol)

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Abstract

The formation of double-stranded inclusion complexes (ICs) between γ-cyclodextrin (γ-CD) and non-modified poly(ethylene glycol) (PEG) was reported to be of trace yield, while in the present work, tunable inclusion complexes between γ-CD and non-modified PEG were successfully prepared by choosing suitable γ-CD concentrations and PEG molecular weights. The obtained γ-CD/PEG ICs showed double-stranded structure whose yield, appearance, and forming rate were significantly affected by PEG molecular weight and temperature as revealed by means of optical microscopy, XRD, DSC, 1H NMR, and ITC. This improved understanding on how to control the formation of double-stranded inclusion complexes should be very helpful for preparation of more sophisticated molecular machines.

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Acknowledgments

The support by the NSFC Grants (51273063 and 21476143), the Fundamental Research Funds for the Central Universities, the high school specialized research fund for the doctoral program (20110074110003), and 111 Project Grant (B08021) are gratefully acknowledged.

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Authors and Affiliations

  1. State-Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, People’s Republic of China

    Kai Huang, Li Li, Jie Wang, Zhiming Zhou & Xuhong Guo

  2. Engineering Research Center of Xinjiang Bingtuan of Materials-oriented Chemical Engineering, Shihezi University, Xinjiang, 832000, People’s Republic of China

    Xuhong Guo

Authors
  1. Kai Huang
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  2. Li Li
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  3. Jie Wang
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  4. Zhiming Zhou
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Correspondence to Li Li.

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Huang, K., Li, L., Wang, J. et al. Tunable double-stranded inclusion complexes of γ-cyclodextrin threaded onto non-modified poly(ethylene glycol). Colloid Polym Sci 294, 311–319 (2016). https://doi.org/10.1007/s00396-015-3788-0

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  • DOI: https://doi.org/10.1007/s00396-015-3788-0

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