Abstract
Rapidly solidified hypereutectic Al–3Ni–3Sb were successfully prepared by the technique of melt–spinning at different solidification rates. The phases appear in the hypereutectic Al–3Ni–3Sb as–cast and rapidly solidified samples were revealed to be Al3Ni, AlSb intermetallic, and the α–Al. To better understand the Al3Ni intermetallic, we made more etching and examined by the FE–SEM microscope. It was observed that the change in the size of Al3Ni intermetallic particles because of rapid solidification was quite remarkable. While the particle size of Al3Ni intermetallic rods was approximately 450 ± 20 nm in conventional cast alloy, it became approximately 45 ± 3 nm in the rapidly solidified alloys. Compared to ingot samples, the microhardness value increased more than twice in melt–spun samples. The significant change in microhardness was due to the shrinkage of the Al3Ni intermetallic structure on the surface of the alloy.
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G. Ham, M. Baek, J. Kin, S. Lee, K. Lee, Effect of heat treatment on tensile and fatigue deformation behavior of extruded Al–12 wt%Si alloy. Met. Mater. Int. 23, 35–42 (2017)
L. Fang, Y. Fuxiao, Z. Dazhi, Z. Liang, Microstructure and mechanical properties of an Al–12.7Si–0.7Mg alloy processed by extrusion and heat treatment. Mater. Sci. Eng. A 528, 3786–3790 (2011)
Y. Du, Y.A. Chang, B. Huang, W. Gong, Z. Jin, H. Xu, Z. Yuan, Y. Liu, Y. He, F.Y. Xie, Diffusion coefficients of some solutes in fcc and liquid Al: critical evaluation and correlation. Mater. Sci. Eng. A 363(1–2), 140–151 (2003)
Y. Du, Y.A. Chang, B. Huang, Y. He, F.Y. Xie, Diffusion coefficients of some solutes in fcc and liquid Al: critical evaluation and correlation. Mater. Sci. Eng., A 363, 140–151 (2003)
E. Karaköse, M. Keskin, Morphological characteristic of the conventional and melt–spun Al–10Ni–5.6Cu (in wt%) alloy. Mater. Charact. 60, 1569–1577 (2009)
E. Karaköse, M. Keskin, Structural investigations of mechanical properties of Al based rapidly solidified alloys. Mater. and Design 32, 4970–4979 (2011)
L.H. Yong, J.S. Hun, L.S. Yong, K.K. Hyun, Alloying of cold–sprayed Al–Ni composite coatings by post–annealing. Appl. Surf Sci. 253, 3496–3502 (2002)
M. Fatih Kilicaslan, E. Karakose, Depth sensing indentation analyses of hypereutectic Al–10Ni – XSc (X = 0, 1, 2) Alloys. Met. Mater. Int. 23(3), 473–480 (2017)
C. Suwanpreecha, P. Pandee, U. Patakham, C. Limmaneevichitr, New generation of eutectic Al–Ni casting alloys for elevated temperature services. Mater. Sci. Eng. A 709, 46–54 (2018)
H. Okamoto, Al–Ni (aluminium–nickel). J. Phase Equilibria Diffus. 25(4), 394–394 (2004)
K. Saksl, D. Vojtech, J. Durisin, in situ XRD studies on Al–Ni and Al–Ni–Sr alloys prepared by rapid solidification. J. Alloy. Comp. 464(1–2), 95–100 (2008)
Y. Fan, M. Makhlouf, The Al–Al3Ni eutectic reaction: crystallography and mechanism of formation. Metall. Mater. Trans. 46(9), 3808–3812 (2015)
Y. Fan, K. Huang, M. Makhlouf, Precipitation strengthening in Al–Ni–Mn alloys. Metall. Mater. Trans. 46(12), 5830–5841 (2015)
F. D. George, J. A. Ford, M. J. Salkind, The effect of fiber orientation and morphology on the tensile behavior of Al3Ni whisker reinforced aluminum. In: STP438-EB Metal Matrix Composites, 59-75. West Conshohocken, PA: ASTM International, (1968). https://doi.org/10.1520/STP43807S
Y. Fan, M.M. Makhlouf, The effect of introducing the AlNi eutectic composition into Al–Zr–V alloys on microstructure and tensile properties. Mater. Sci. Eng. A 654(228), 235 (2016)
T. Koutsoukis, M.M. Makhlouf, Alternatives to the Al–Si Eutectic System in Aluminum Casting Alloys. Inter. Metalcast. 10, 342–347 (2016)
N.A. Belov, A.N. Alabin, D.G. Eskin, Improving the properties of cold–rolled Al–6%Ni sheets by alloying and heat treatment. Scr. Mater. 50(1), 89–94 (2004)
E. Karaköse, M. Keskin, Effect of solidification rate on the microstructure and microhardness of a melt–spun Al–8Si–1Sb alloy. J. Alloy. Comp. 466, 111–118 (2009)
M.F. Kilicaslan, E. Karaköse, Production of CNT–bearing melt–spun Al–2Sc–0.05 CNT alloys. J. Alloy. Comp. 738, 182–187 (2018)
E. Karaköse, H. Çolak, Effect of cooling rate and Mg addition on the structural evaluation of rapidly solidified Al–20wt% Cu–12wt% Fe alloy. Mater. Charact. 121, 68–75 (2016)
C.S. Kiminami, N.D. Basim, M.J. Kaufman, M.F. Amateau, T.J. Eden, J.M. Galbraith, Challenges in the development of aluminium–based bulk amorphous alloys. Key Eng. Mater. 189–191, 503–508 (2001)
A. Inoue, H. Kimura, Fabrications and mechanical properties of bulk amorphous, nanocrystalline, nanoquasicrystalline alloys in aluminum–based system. J. Light Met. 1, 31–41 (2001)
D. Srinivasan, K. Chattopadhyay, Hardness of high strength nanocomposite Al–X–Zr (X=Si, Cu, Ni) alloys. Mat. Sci. Eng. A 375–377, 1228–1234 (2004)
B.J. McKay, P. Cizek, P. Schumacher, K.A.Q. O’Reilly, Heterogeneous nucleation in an Al–Ni–Si alloy studied using a metallic glass technique. Mat. Sci. Eng. A 304–306, 240–244 (2001)
L. Yang, H. Bin, L. Bin, N. Anmin, G. Qinfen, W. Jianfeng, L. Qian, Insight into Si poisoning on grain refinement of Al–Si/Al–5Ti–B system. Acta Mater. 2020, 51–65 (1871)
L. Qiang, Q. Feng, D. Bai–Xin, G. Xiang, S. Shi–Li, Y. Hong–Yu, J. Qi–Chuan, Processing, multiscale microstructure refinement and mechanical property enhancement of hypoeutectic Al–Si alloys via in situ bimodal–sized TiB2 particles. Mater. Sci. Eng. A 77710, 139081 (2020)
H. Hailin, Y. Youping, H. Shiquan, G. Wanfu, Z. Yuxun, Effects of thermomechanical treatment on grain refinement, second–phase particle dissolution, and mechanical properties of 2219 Al alloy. J Mater Process Technol 278, 116506 (2020)
A. Zajaczkowski, J. Botor, Thermodynamics of the Al–Sb system determined by vapour pressure measurements. Z. Metallkd. 86, 590–596 (1995)
K. Yamaguchi, M. Yoshizawa, Y. Takeda, K. Kameda, K. Itagaki, Measurement of thermodynamic properties of Al–Sb system by calorimeters. Mater. Trans. JIM 36, 432–437 (1995)
J. Zhu, T. Zhou, M. Zha, C. Li, J. Li, C. Wang, C. Gao, H. Wang, Q. Jiang, Microstructure and wear behaviour of Al-20Mg2Si alloy with combined Zr and Sb additions. J. Alloy. Compd. 767, 1109–1111 (2018)
F. Guo, W. Wang, W. Yu, Y. Zhang, S. Pan, Z. Zhou, D. Liu, J. Qin, Y. Wang, X. Tian, Enhanced nucleation and refinement of eutectic Si by high number-density nano-particles in Al–10Si–0.5Sb alloys. Mater. Des. 117, 382–389 (2017)
M. Okayasu, S. Takeuchi, S. Wu, T. Ochi, Effects of Sb, Sr, and Bi on the material properties of cast Al-Si-Cu alloys produced through heated mold continuous casting. J. Mech. Sci. Technol. 30, 1139–2114 (2016)
M. Gogebakan, O. Uzun, T. Karaaslan, M. Keskin, Hardness and microstructural characteristics of rapidly solidified Al–8–16 wt%Si alloys. J. Alloys Compd. 142, 87–92 (2003)
O. Uzun, F. Yilmaz, U. Kolemen, N. Basman, Sb effect on micro structural and mechanical properties of rapidly solidified Al–12Si alloy. J. Alloys Compd. 509, 21–26 (2011)
S.M. Lee, H.J. Jeon, B.H. Kim, W.T. Kim, D.H. Kim, Solidification sequence of the icosahedral quasicrystal forming Al–Cu–Fe alloys. Mater. Sci. Eng. A 304–306, 871–878 (2001)
E. Karaköse, M. Keskin, Microstructures and microhardness evolutions of melt–spun Al–8Ni–5Nd–4Si alloy. Mater. Charact. 65, 37–47 (2012)
M.F. Kilicaslan, F. Yilmaz, S.J. Hong, O. Uzun, Effect of Co on Si and Fe containing intermetallic compounds (IMCs) in Al–20Si–5Fe alloys. Mater. Sci. Eng. A 556, 716–721 (2012)
E. Karaköse, M.F. Kılıçaslan, H. Çolak, Formation of novel rice–like intermetallic phases and changes in the mechanical, microstructural and electrical properties of Sn–5Sb alloys with addition Ag and Bi. J. Alloy. Comp. 655, 378–388 (2016)
O.C. Hellman, J.A. Vandenbroucke, J. Rüsing, D. Isheim, D.N. Seidman, Analysis of three–dimensional atom–probe data by the proximity histogram. Microsc. Microanal. 6(5), 437–444 (2000)
D.D. Himbeault, J.R. Cahoon, Creep regimes for directionally solidified Al– Al3N eutectic composite. Metall. Mater. Trans. A 24(12), 2721–2730 (1993)
R. Elliot, Eutectic solidification. Int. Met. Rev. 22, 161–186 (1977)
Y. Fukui, N. Yamanaka, Y. Enokida, Bending strength of an Al–Al3Ni functionally graded material. Compos. Part B: Eng. 28(1), 37–43 (1997)
C.L. Pereira, L.F. Gomes, A. Garcia, J.E. Spinelli, Comparing the roles of Sb and Bi on microstructures and application properties of the Al–15% Si alloy. J. Alloys Compd 878, 160343 (2021)
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This study was financed by Erciyes University Research Funds, Grant No. FBA–2019–8863.
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Karaköse, E., Keskin, M. Change of intermetallic phases and mechanical features in rapidly solidified hypereutectic Al–3Ni–3Sb alloy. Appl. Phys. A 127, 850 (2021). https://doi.org/10.1007/s00339-021-04982-z
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DOI: https://doi.org/10.1007/s00339-021-04982-z