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Rare-earth (Dy)-doped (GeS2)80(In2S3)20 thin film: influence of annealing temperature in argon environment on the linear and nonlinear optical parameters

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Abstract

We report the optical properties of thermally evaporated rare-earth (Dy) doped (GeS2)80(In2S3)20 thin film. Film of thickness 1100 nm has been deposited on a microscopic glass slide, and the as-prepared thin film has been characterized using X-ray diffraction, energy dispersive spectroscopy and UV–visible–near infrared spectroscopy. With annealing temperature, the refractive index is noticed to decrease from 2.51 to 2.27, while the optical bandgap is observed to increase from 2.03 to 2.29. The dispersion of the refractive index n for as prepared and annealed thin films have discussed using the single oscillator model proposed by the Wemple–Di Domenico relationship. The observed value of Eo (5.31–4.40 eV) and dispersion energy Ed (28.22–18.18 eV) are decreasing for as prepared and annealed thin films. The increase of bandgap has been explained in terms of the disorder in the system.

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References

  1. D.C. Sati, A. Dahshan, P. Sharma, Appl. Mater. Today 17, 142–158 (2019)

    Article  Google Scholar 

  2. V. Sharma, S. Sharda, N. Sharma, S.C. Katyal, P. Sharma, Prog. Solid State Chem. 54, 31–44 (2019)

    Article  Google Scholar 

  3. K.A. Aly, Y. Saddeek, A. Dahshan, Appl. Phys. A Mater. Sci. Process. 122(3), 1–6 (2016)

    Article  Google Scholar 

  4. K.A. Aly, J. Non Cryst. Solids 355(28–30), 1489–1495 (2009)

    Article  ADS  Google Scholar 

  5. A. Dahshan, S.R. Alharbi, K.A. Aly, Y. Saddeek, J. Therm. Anal. Calorim. 140(1), 125–131 (2020)

    Article  Google Scholar 

  6. P. Sharma, A. Dahshan, V.K. Sehgal, K.A. Aly, IEEE Trans. Electron Devices 65(8), 3408–3413 (2018)

    Article  ADS  Google Scholar 

  7. P. Sharma, N. Sharma, S. Sharda, S.C. Katyal, V. Sharma, Prog. Solid State Chem. 44(4), 131–141 (2016)

    Article  Google Scholar 

  8. S. Chand, E. Sharma, P. Sharma, J. Alloy. Compd. 770, 1173–1180 (2019)

    Article  Google Scholar 

  9. Z. Li, C. Lin, Q. Nie, S. Dai, J. Am. Ceram. Soc. 96(1), 125–129 (2013)

    Article  Google Scholar 

  10. M.J. MacLachlan, S. Petrov, R.L. Bedard, I. Manners, G.A. Ozin, Angew. Chem. Int. Ed. 37(15), 2075–2079 (1998)

    Article  Google Scholar 

  11. R. Swanepoel, J. Phys. E Sci. Instrum. 16(12), 1214–1222 (1983)

    Article  ADS  Google Scholar 

  12. J. Tauc, Mater. Res. Bull. 3(1), 37–46 (1968)

    Article  Google Scholar 

  13. K.A. Aly, Y.B. Saddeek, A. Dahshan, Opt. Mater. 109, 110341 (2020)

    Article  Google Scholar 

  14. H.H. Hegazy, A. Dahshan, K.A. Aly, Mater. Res. Express 6(2), 025204 (2019)

    Article  ADS  Google Scholar 

  15. S.S. Fouad, G.A.M. Amin, M.S. El-Bana, J. Non Cryst. Solids 481, 314–320 (2018)

    Article  ADS  Google Scholar 

  16. E.R. Shaaban, Y.A.M. Ismail, H.S. Hassan, J. Non Cryst. Solids 376, 61–67 (2013)

    Article  ADS  Google Scholar 

  17. M.F. Thorpe, J. Phys. C Solid State Phys. 6(4), L75–L77 (1973)

    Article  ADS  Google Scholar 

  18. E.A. Davis, N.F. Mott, Philos. Mag. J. Theor. Exp. Appl. Phys. 22(179), 0903–0922 (1970)

    Google Scholar 

  19. L. Tichy, H. Ticha, P. Nagels, R. Callaerts, J. Non Cryst. Solids 240(1–3), 177–181 (1998)

    Article  ADS  Google Scholar 

  20. K.A. Aly, A. Dahshan, A.M. Abousehly, Phil. Mag. 88(1), 47–60 (2008)

    Article  ADS  Google Scholar 

  21. A.S. Hassanien, I. Sharma, Optik 200, 163415 (2020)

    Article  ADS  Google Scholar 

  22. N.F. Mott, E.A. Davis, R.A. Street, Philos. Mag. 32(5), 961–996 (1975)

    Article  ADS  Google Scholar 

  23. A.M. Adam, E. Lilov, E.M.M. Ibrahim, P. Petkov, L.V. Panina, M.A. Darwish, J. Mater. Process. Technol. 264, 76–83 (2019)

    Article  Google Scholar 

  24. K.A. Aly, A.M. Abousehly, M.A. Osman, A.A. Othman, Phys. B 403(10–11), 1848–1853 (2008)

    Article  ADS  Google Scholar 

  25. A.S. Soltan, M. Abu El-Oyoun, A.A. Abu-Sehly, A.Y. Abdel-Latief, Mater. Chem. Phys. 82(1), 101–106 (2003)

    Article  Google Scholar 

  26. S.H. Wemple, M. DiDomenico, Phys. Rev. B 3(4), 1338–1351 (1971)

    Article  ADS  Google Scholar 

  27. S.H. Wemple, Phys. Rev. B 7(8), 3767–3777 (1973)

    Article  ADS  Google Scholar 

  28. K. Tanaka, Thin Solid Films 66(3), 271–279 (1980)

    Article  ADS  Google Scholar 

  29. A.K. Walton, T.S. Moss, Proc. Phys. Soc. 81(3), 509–513 (1963)

    Article  ADS  Google Scholar 

  30. A.S. Hassanien, A.A. Akl, Phys. B Condens. Matter 576, 411718 (2020)

    Article  Google Scholar 

  31. P. Halevi, F. Ramos-Mendieta, Phys. Rev. Lett. 85(9), 1875–1878 (2000)

    Article  ADS  Google Scholar 

  32. C.C. Wang, Phys. Rev. B 2(6), 2045–2048 (1970)

    Article  ADS  Google Scholar 

  33. J.J. Wynne, Phys. Rev. 178(3), 1295–1303 (1969)

    Article  ADS  Google Scholar 

  34. H. Tichá, L. Tichý, J. Optoelectron. Adv. Mater. 4(2), 381–386 (2002)

    Google Scholar 

  35. T.S. Moss, Phys. Status Solidi B Basic Res. 131(2), 415–427 (1985)

    Article  ADS  Google Scholar 

  36. N.M. Ravindra, V.K. Srivastava, Infrared Phys. 19(5), 603–604 (1979)

    Article  ADS  Google Scholar 

  37. A. Lamichhane, N.M. Ravindra, Energy gap–refractive index relations in Perovskites. Materials (Basel, Switzerland) 13(8), 1917 (2020)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

The author (A. Dahshan) gratefully thank the Deanship of Scientific Research at King Khalid University for the financial support through research groups program under Grant number (R.G.P.2/113/41). Dr Deep Shikha Sharma is acknowledged for language editing of the manuscript.

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Correspondence to Pankaj Sharma.

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Sharma, P., Sharma, V., Sharma, E. et al. Rare-earth (Dy)-doped (GeS2)80(In2S3)20 thin film: influence of annealing temperature in argon environment on the linear and nonlinear optical parameters. Appl. Phys. A 127, 68 (2021). https://doi.org/10.1007/s00339-020-04170-5

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