Abstract
Carbon nanotubes (CNTs) grown on electrospun polyacrylonitrile-based carbon nanofibers (CNFs) via chemical vapor deposition were studied in this paper. Analyses of Raman spectra and X-ray diffraction patterns revealed that incorporation of CNTs could improve the crystalline and structure integrity of the obtained CNFs/CNTs composite. About 7.4 wt% of CNTs were grown on the electrospun CNFs confirmed by thermal gravimetric analysis. The electrochemical results showed that the surface activity and the cycle retention of the CNFs/CNTs composite were enhanced due to its three-dimensional nanostructure, enhanced pore distribution, and good conductivity. The CNFs/CNTs composite offers a great potential for high-performance lithium-ion batteries as the electrode.
Similar content being viewed by others
References
L.W. Ji, Z. Lin, A.J. Medford, X.W. Zhang, Carbon 47, 3346 (2009)
L.W. Ji, X.W. Zhang, Carbon 47, 3219 (2009)
H.S. Choi, J.G. Lee, H.Y. Lee, S.W. Kim, C.R. Park, Electrochim. Acta 56, 790 (2010)
X. Fan, L. Zou, Y.P. Zheng, F.Y. Kang, W.C. Shen, Electrochem. Solid-State Lett. 12, A199 (2009)
L.W. Ji, X.W. Zhang, Electrochem. Commun. 11, 795 (2009)
Z.X. Dong, S.J. Kennedy, Y.Q. Wu, J. Power Sources 196, 4886 (2011)
L. Zou, L. Gan, R.T. Lv, M.X. Wang, Z.H. Huang, F.Y. Kang, W.C. Shen, Carbon 49, 89 (2011)
J.B. Mu, B. Chen, Z.C. Guo, M.Y. Zhang, Z.Y. Zhang, C.L. Shao, Y.C. Liu, J. Colloid Interface Sci. 356, 706 (2011)
C.S. Sharma, H. Katepalli, A. Sharma, M. Madou, Carbon 49, 1727 (2011)
X.F. Tang, Y. Liu, H.Q. Hou, T.Y. You, Talanta 83, 1410 (2011)
Z. Kurban, A. Lovell, D. Jenkins, S. Bennington, I. Loader, A. Schober, N. Skipper, Eur. Polym. J. 46, 1194 (2010)
S. Sinha-Ray, A.L. Yarin, B. Pourdeyhimi, Carbon 48, 3575 (2010)
Z.X. Yang, G.D. Du, C.Q. Feng, S.A. Li, Z.X. Chen, P. Zhang, Z.P. Guo, X.B. Yu, G.N. Chen, S.Z. Huang, H.K. Liu, Electrochim. Acta 55, 5485 (2010)
L. Zhang, F. Li, Electrochim. Acta 55, 6695 (2010)
C. Kim, K.S. Yang, M. Kojima, K. Yoshida, Y.J. Kim, Y.A. Kim, M. Endo, Adv. Funct. Mater. 16, 2393 (2006)
H.Q. Hou, D.H. Reneker, Adv. Mater. 16, 69–73 (2004)
A.K. Mishra, T. Arockiadoss, S. Ramaprabhu, Chem. Eng. J. 162, 1026 (2010)
M.A. Pasha, M. Ranjbar, M.A. Vesaghi, A. Shafiekhani, Appl. Surf. Sci. 257, 1511 (2010)
H.C. Su, C.M. Lin, S.J. Yen, Y.C. Chen, C.H. Chen, S.R. Yeh, W. Fang, H. Chen, D.J. Yao, Y.C. Chang, T.R. Yew, Biosens. Bioelectron. 26, 220 (2010)
N. Tumilty, L. Kasharina, T. Prokhoda, B. Sinelnikov, R.B. Jackman, Carbon 48, 3027 (2010)
F. Kokai, K. Uchiyama, T. Shimazu, A. Koshio, Appl. Phys. A 101, 497 (2010)
S. Basri, S.K. Kamarudin, W.R.W. Daud, Z. Yaakub, Int. J. Hydrog. Energy 35, 7957 (2010)
E. Maccallini, T. Tsoufis, A. Policicchio, S. La Rosa, T. Caruso, G. Chiarello, E. Colavita, V. Formoso, D. Gournis, R.G. Agostino, Carbon 48, 3434 (2010)
Z. Yang, Q. Zhang, G. Luo, J.-Q. Huang, M.-Q. Zhao, F. Wei, Appl. Phys. A 100, 533 (2010)
M. Aksak, Y. Selamet, Appl. Phys. A 100, 213 (2010)
H.B. Li, W.J. Wang, B. Song, R. Wu, J. Li, Y.F. Sun, Y.F. Zheng, J.K. Jian, J. Alloys Compd. 503, L34 (2010)
G. Pilatos, E.C. Vermisoglou, G.E. Romanos, G.N. Karanikolos, N. Boukos, V. Likodimos, N.K. Kanellopoulos, Adv. Funct. Mater. 20, 2500 (2010)
B. Li, X.H. Cao, H.G. Ong, J.W. Cheah, X.Z. Zhou, Z.Y. Yin, H. Li, J.L. Wang, F. Boey, W. Huang, H. Zhang, Adv. Mater. 22, 3058 (2010)
Z.G. Zhao, L.J. Ci, H.M. Cheng, J.B. Bai, Carbon 43, 663 (2005)
N. Sonoyama, M. Ohshita, A. Nijubu, H. Nishikawa, H. Yanase, J. Hayashi, T. Chiba, Carbon 44, 1754 (2006)
C. Lai, Q.H. Guo, X.F. Wu, D.H. Reneker, H. Hou, Nanotechnology 19, 195303 (2008)
D.C.D. Nath, V. Sahajwalla, Appl. Phys. A 104, 539 (2011)
Z.Y. Li, H.M. Huang, T.C. Shang, F. Yang, W. Zheng, C. Wang, S.K. Manohar, Nanotechnology 17, 917 (2006)
J. Li, E.H. Liu, W. Li, X.Y. Meng, S.T. Tan, J. Alloys Compd. 478, 371 (2009)
Y.H. Yu, Q. Yang, D.H. Teng, X.P. Yang, S. Ryu, Electrochem. Commun. 12, 1187 (2010)
Acknowledgement
Financial support of this work was provided by the National Basic Research Program of China (Grant No. 2010CB934700).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhao, L., Li, Y., Zhao, Y. et al. Carbon nanotubes grown on electrospun polyacrylonitrile-based carbon nanofibers via chemical vapor deposition. Appl. Phys. A 106, 863–869 (2012). https://doi.org/10.1007/s00339-012-6770-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-012-6770-4