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Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates

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Abstract

New piperazine-based polymerizable monomers were synthesized to modify adhesive properties of fluoromethacrylic copolymer. The new monomers showed good ability to radical copolymerization with fluoroalkylmethacrylates. Amorphous glassy terpolymers were prepared with random distribution units in the macromolecules and weight-average molecular weight (M w) 110,000–130,000. The ratio of monomer units in the obtained copolymer is close to the ratio of the monomers in the starting mixture. The terpolymers exhibited excellent solubility in tetrahydrofuran (THF), acetone and α,α,α-trifluorotoluene (TFT). The introduction of new monomers to the macromolecules increased the glass-transition temperatures (T g) of terpolymers, significantly improved their thermal stability and adhesion to the aluminum substrate.

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Acknowledgments

This work was supported by the Russian Science Foundation (No. 14-13-00826).

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Authors and Affiliations

  1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 9, 630090, Novosibirsk, Russia

    Inna K. Shundrina, Aleksandra D. Bukhtoyarova, Vladimlen V. Russkikh & Vladimir V. Shelkovnikov

  2. International Tomography Center, Institutskaya 3a, 630090, Novosibirsk, Russia

    Dmitry A. Parkhomenko

  3. Novosibirsk State University, 630090, Novosibirsk, Russia

    Inna K. Shundrina

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  1. Inna K. Shundrina
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  2. Aleksandra D. Bukhtoyarova
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  3. Vladimlen V. Russkikh
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  4. Dmitry A. Parkhomenko
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  5. Vladimir V. Shelkovnikov
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Correspondence to Inna K. Shundrina.

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Shundrina, I.K., Bukhtoyarova, A.D., Russkikh, V.V. et al. Synthesis and properties of novel random copolymers made from N-acryloyl piperazine-based monomers and fluoroalkylmethacrylates. Polym. Bull. 72, 2783–2796 (2015). https://doi.org/10.1007/s00289-015-1435-z

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  • DOI: https://doi.org/10.1007/s00289-015-1435-z

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