Abstract
The intermetallic compounds NpAI2, NpAI3, and NpAI4 have been prepared, and examined by X-ray diffraction methods. The compounds are isostructural with the corresponding U-AI compounds. NpAI2 is face-centered cubic with a = 7.785Ä and has the MgCu2 structure. NpAI3 is simple cubic with a = 4.262Ä and has the AuCu3 structure. NpAI4 is body-centered orthorhombic with a = 4.42Ä, b = 6.26Ä, and c = 13.71Ä. The published description for the atomic positions in UAI4 applies also to NpAI4.
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P. Gordon and A. R. Kaufmann: Trans. AIME (1950) 188, p. 182; Journal of Metals (January 1950).
B. S. Borie: Trans. AIME (1951) 191, p. 800; Journal of Metals (September 1951).
R. E. Rundle and A. S. Wilson: Acta Crystallographica (1949) 2, p. 148.
E. F. Westrum: Paper in “The Transuranium Elements.” Edited by G. T. Seaborg, J. J. Katz, and W. M. Manning. (1949) p. 938. New York. McGraw-Hill Book Co.
S. Fried and N. Davidson: Journal ACS (1948) 70, p. 3539.
O. J. C. Runnalls: Canadian Journal of Chemistry (1953) 31, p. 694.
W. H. Zachariasen: Paper in “The Transuranium Elements.” Edited by G. T. Seaborg, J. J. Katz, and W. M. Manning. (1949) p. 1490. New York. McGraw-Hill Book Co.
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Discussion on this paper, TP 3654E, may be sent, 2 copies, to AIME by April 1, 1954. Manuscript, July 3, 1953. New York Meeting, February 1954.
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Runnalls, O.J.C. Neptunium-Aluminum Intermetallic Compounds. JOM 5, 1460–1462 (1953). https://doi.org/10.1007/BF03397636
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DOI: https://doi.org/10.1007/BF03397636