Abstract
The atomic structure of the amorphous metallic alloy Al83.5Ni9.5Si1.4La5.6 is investigated based on the analysis of the experimental atomic radial distribution function (ARDF) in the fragmentary model. A comparative analysis of the most probable interatomic distances in the alloy and possible compounds based on it has demonstrated the presence of crystalline nuclei of the following phases: Al3La, Al3Ni, Al2.12La0.88, Al3Ni5, and Al. The largest ones (1–2 nm) are nuclei of the Al3Ni and Al compound, while the majority nuclei of all the other phases had sizes of about 7 Å. Al and Al3Ni, as well as Al11La3 and Al5.56LaNi1.44 are observed in the crystallized alloy.
Similar content being viewed by others
References
Luzgin, D.V. and Inoue, A., Bulk metallic glasses. Formation, structure, properties, and applications, in Handbook of Magnetic Materials, Buschow, K.H.J., Ed., Amsterdam: Elsevier, 2013, vol. 21, pp. 131–171.
Sudzuki, K., Fudzimori, Kh., and Khasimoto, K., Amorfnye metally (Amorphous Metals), Moscow: Metallurgiya, 1987.
Glezer, A.M., Creation principles of new-generation multifunctional structural materials, Phys. Usp., 2012, vol. 55, no. 5, pp. 522–529.
Minaev, V.S., Timoshenkov, S.P., and Kalugin, V.V., Nanogeteromorfnaya struktura i relaksatsiya nekristallicheskogo veshchestva: uchebnoe posobie (Nanoheteromorphous Structure and Relaxation of Non-Crystalline Matter State, The School-Book), Moscow: MIET, 2010.
Aleinikova, K.B., Zinchenko, E.N., and Likhach, N.I., Diffraction methods for analysing nanodispersed materials, Zavod. Lab., Diagn. Mater., 2005, vol. 71, no. 4, pp. 27–31.
Aleynikova, K.B. and Zinchenko, E.N., Fragment model as a phase analysis method for diffraction amorphous materials, J. Struct. Chem., 2009, vol. 50, suppl., pp. S93–S99.
Vainshtein, B.K., To the theory of radial distribution method, Sov. Phys. Crystallogr., 1957, vol. 2, no. 1, pp. 24–31.
Aleinikova, K.B. and Likhach, N.I., Fragmentary model as applied to analysis of spectroscopically pure vitreous SiO2, Glass Phys. Chem., 2005, vol. 31, no. 5, pp. 648–660.
Aleynikova, K.B., Zmeykin, A.A., Zinchenko, E.N., and Ievlev, V.M., Analysis of the atomic structure of metallic glass of composition Al87Ni10Nd3 with the use of a fragmentary model, Glass Phys. Chem., 2012, vol. 38, no. 1, pp. 71–76.
Nabitovich, I.D., Stetsiv, Ya.I., and Voloshchuk, Ya.V., Determination of the coherent and background intensity from the experimental electron scattering curve, Sov. Phys. Crystallogr., 1967, vol. 12, no. 4, pp. 513–516.
Havinga, E.E., Influence of repulsive energy on structural parameters of close-packed metal structures, J. Less-Common Met., 1975, vol. 41, pp. 241–254.
Tonejc, A., Rocak, D., and Bonefacic, A., Mechanical and structural properties of al-ni alloys rapidly quenched from the melt, Acta Metall., 1971, vol. 19, pp. 311–316.
Buschow, K.H.J., The lantanum-aluminium system, Philips Res. Rep., 1965, vol. 20, pp. 337–348.
Enami, K. and Nenno, S., New ordered phase in tempered 63.8 Ni-1Co-Al martensite, Trans. Jpn. Inst. Met., 1978, vol. 19, pp. 571–580.
ICDD, PDF-2, no. 00-024-0501.
ICDD, PDF-2, no. 00-002-0416.
ICDD, PDF-2, no. 01-073-3304.
Gomes de Mesquita, A.H., and Buschow, K.H.J., The crystal structure of so-called α-LaAl4 (La3A11), Acta Crystallogr., 1967, vol. 22, pp. 497–501.
Gout, D., Bendow, E., Gourdon, O., and Miller, G., Composition-structure relationships in polar intermetallics: experimental and theoretical studies of La Ni (1 + x) Al (6–x) (x = 0.44), Inorg. Chem., 2004, vol. 43, pp. 4604–4609.
Aleinikova, K.B. and Zmeikin, A.A., Fragmentary model and atomic structure of amorphous alloy Al83Ni10La7, Vestn. Voronezh. Univ., 2009, no. 1, pp. 5–9.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © K.B. Aleinikova, E.N. Zinchenko, A.A. Zmeikin, 2018, published in Fizika i Khimiya Stekla.
Rights and permissions
About this article
Cite this article
Aleinikova, K.B., Zinchenko, E.N. & Zmeikin, A.A. Atomic Structure of the Amorphous Metallic Alloy Al83.5Ni9.5Si1.4La5.6. Glass Phys Chem 44, 307–313 (2018). https://doi.org/10.1134/S108765961804003X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S108765961804003X