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The action of hexamethylene tetramine on phenols and the methyl esters of phenol carboxylic acids

Part II. The synthesis and study of methyl-2 ∶ 3 ∶ 4 trihydroxy-5-formyl-benzoate

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Proceedings of the Indian Academy of Sciences - Section A Aims and scope Submit manuscript

Summary

  1. 1.

    Methyl-2∶3∶4-trihydroxy benzoate was formylated by the action of hexamethylene-tetramine in glacial acetic acid and methyl-2∶3∶4-trihydroxy-5-formyl benzoate was obtained. Several derivatives of the formyl ester were prepared and the structure established.

  2. 2.

    Formylation of several hydroxy compounds was also attempted.

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References

  1. Desai and RadhaProc. Ind. Acad. Sci., A, 1940,11, 422.

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  2. Robinson and ShahJ., 1934, 1497.

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Desai, R.D., Radha, K.S. & Shah, R.C. The action of hexamethylene tetramine on phenols and the methyl esters of phenol carboxylic acids. Proc. Indian Acad. Sci. (Math. Sci.) 23, 179 (1946). https://doi.org/10.1007/BF03170934

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  • DOI: https://doi.org/10.1007/BF03170934

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