Abstract
A systematic study of the kinetics of photo-chemical polymerisation of acrylamide using the system anthraquinone sulphonate-NaCl-HClO4 under deaerated condition in aqueous solution has been done. The determinations of the monomer disappearance (bromometry), the sensitiser disappearance (spectrophotometry) and chainlengths of polymers with respect to light intensity, concentration of monomer, light absorption fraction (k e ) of sensitiser, etc., have been carried out. An overall kinetic mechanism is given in the light of experimental results.
Similar content being viewed by others
References
Dainton, F. S. and Tordoff, M.Trans. Faraday Soc., 1957,53, 666.
Evans, M. G. and Uri, N.Nature, 1949,164, 404.
Santappa, M...J. Madras Univ., 1954,24 B, 91, 279.
Venkatarao, K. and Santappa, M.J. Polymer Sci., 1967,5, 637.
Sakamoto, M., Hayashi, K. and Okamura, S. —Ibid., 1965,3 B, 205.
Weiss, J...J. Soc. Dyers and Colourists, 1949,65, 719.
Usui, Y., Obata, H. and Koizumi, M.Bull. Chem. Soc. Japan, 1961,34, 1050.
Sheriff, A. I. and Santappa, M.J. Polymer Sci., 1965,3(A1), 3131.
Dainton, F. S. and Tordoff, M.Trans. Faraday Soc., 1957,53, 499.
Geacintov, N., Stannett, V., Abrahamson, E. W. and Hermans, J. J.J. Appl. Polymer Sci., 1960, p. 54.
Md. Sheriff, A.I. and Santappa, M.Proc. Ind. Acad. Sci., 1965,62, 56.
Jijee, K., Mahadevan, V. and Santappa, M. —Ibid., 1966,64, 128.
Shepp, A., Cheberek, S. and MacNeil, R.J. Phys. Chem., 1962,66, 2563.
Toppet, S., Delzenne, G. and Smets, G.J. Polymer Sci., 1964,2 A, 1539.
Wilkinson, F...J. Phys. Chem., 1962,66, 2569.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Santappa, M., Anwaruddin, Q. Vinyl polymerisation. Proc. Indian Acad. Sci. 68, 186–194 (1968). https://doi.org/10.1007/BF03049419
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03049419