Summary
From the theoretical analysis of our experimental work we can conclude hat the phenomenon of the energy migration, between the molecules of an aromatic compound, seems to take place in those compounds which show intense peaks in their absorption spectra. We believe that the excitation energy is transferred between the vibrational excitation levels of different molecules of the same kind without photon interchange, by a mechanism of excitonic type (1) (vibronic excitons), before the vibrational relaxation time under certain conditions which are stated below.
Similar content being viewed by others
References
Th. Förster: inModern Quantum Chemistry, Section III B (Academic Press, London, 1965), p. 93.
Th. Förster:Discuss. Faraday Soc,27, 7 (1959).
E. G. Mc Rae:Aust. J. Chem.,14, 329 (1961).
E. G. Mc Rae:Aust. J. Chem.,16, 295, 315 (1963).
R.E. Merrifield:J. Chem. Phys.,40, 445 (1964).
D. L. Dexter:J. Chem. Phys.,21, 836 (1953).
W. Goad:J. Chem. Phys.,38, 1245 (1963).
K. Katsura:J. Chem. Phys.,40, 3527 (1964).
W. Hauswirth andM. Daniels: inPhotochemistry and Photobiology, Vol. 1 (Academics Press, New York, N.Y., 1976).
See and ref. (1), p. 131.
C. R. C. :Handbook of Chemistry and Physics, The Chem. Rubber Co. Press (U.S.A.).
I. B. Berlman:Fluorescence spectra of Aromatic Molecules (Academic Press, London, 1971).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Philippetis, A.L., Poulopoulos, P.N. Energy migration between the molecules of an aromatic compound at high concentration in liquid and solid solutions. Lett. Nuovo Cimento 40, 457–460 (1984). https://doi.org/10.1007/BF02748415
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF02748415