Abstract
Phase transitions in LiKSO4 have been visually observed in a diamond-anvil cell up to 16 GPa. The observations confirm a symmetry change at 0·9 GPa and a solidstate crystal to amorphous transition at 12 GPa. The crystal exhibits a memory across the crystalline transitions. Interesting microstructural features were observed in the range of the amorphous phase.
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Arora A K and Sakuntala T 1990Solid State Commun. 75 885
Bansal M L 1984Proceedings of III Natl Seminar on Ferroelectrics and Dielectrics, India, p 77
Bhakay-Tamhane S 1978Structural investigations of low-temperature phase transitions in LiKSO 4 and (NH4)2 CuCl4.2H2 O, Ph.D. Thesis, Bombay University
Bhakay-Tamhane S, Sequeira A and Chidambaram R 1984Acta Crystallogr. C40 1648
Born M and Huang K 1962 inDynamical theory of crystal lattices (Oxford: Clarendon Press)
Chaplot S L and Sikka S K 1990 unpublished
Hemley R J, Jephcoat A P, Mao H K, Ming L C and Manghnani M H 1988Nature (London) 334 52
Hemley R J, Chen L C and Mao H K 1989Nature (London) 338 6217
Hsich H and Yip S 1987Phys. Rev. Lett. 59 2760
Kuhs W F, Fenney J L, Vellier C and Bliss D V 1984J. Chem. Phys. 81 3612
Melo F E A, Lemos V, Cerdiera F and Filho J M 1987Phys. Rev. B35 3633
Sankaran H, Sikka S K, Sharma S M and Chidambaram R 1988Phys. Rev. B38 170
Stishov S M and Popova S V 1961Geokhimiya 10 837
Wolf D, Okamato P R, Yip S, Lutsko J F and Kluge M 1990J. Mater. Res. 5 286
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Sankaran, H., Sikka, S.K., Sequeira, A. et al. Visual observation of phase transitions in LiKSO4 under pressure. Bull. Mater. Sci. 14, 1213–1218 (1991). https://doi.org/10.1007/BF02744614
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DOI: https://doi.org/10.1007/BF02744614