Skip to main content
Log in

Improtance of fundamental study in hydrometallurgy

  • The 1995 Extraction and Processing Lecture the Minerals, Metals & Materials Society
  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

Recent developments in modeling and optimization studies using computer technology have had a remarkable effect on all areas of extractive metallurgy. However, a lack of fundamental data regarding, for instance, activities, diffusion coefficients, limiting current densities,etc. obstructs the reliable use of this method. In studying hydrometallurgy, I recognized the importance of fundamental analysis and continued such works throughout my university life. For example, activities of water and solutes of the solution systems H2SO4−Mx(SO4)y−H2O and HCl−MClx−H2O were determined, and the results were employed to analyze the dissolution mechanism of metal oxides as well as metal sulfides in those solutions. In this article, fundamental studies mainly made in my laboratory to understand hydrometallurgical phenomena will be discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M.J. Nicol, C.R.S. Needes, and N.P. Finkelstein: inLeaching and Reduction in Hydrometallurgy, A.R. Burkin, ed., The Institution of Mining and Metallurgy, London, 1975, pp. 1–11.

    Google Scholar 

  2. C.R.S. Needes, M.J. Nicol, and N.P. Finkelstein: inLeaching and Reduction in Hydrometallurgy, A.R. Burkin, ed., The Institution of Mining and Metallurgy, London, 1975, pp. 12–19.

    Google Scholar 

  3. A.N. Kirgintev and A.V. Lukyanov:Russ J. Phys. Chem., 1963, vol. 37, p. 121.

    Google Scholar 

  4. W. Davis, Jr. and H.J. deBruin:J. Inorg. Nucl. Chem., 1969, vol. 26 p. 1069.

    Article  Google Scholar 

  5. H.E. Bent and R.J. Francel:J. Am. Chem. Soc., 1948, vol. 70, p. 643.

    Article  Google Scholar 

  6. A.B. Zdanovskii:Izd. Akad. Nauk SSSR, 1936, vol. 6.

  7. Y. Awakura, K. Matsumoto, and H. Majima:Denki Kagaku, 1984. vol. 52 (10), pp. 659–65.

    CAS  Google Scholar 

  8. H. Majima and Y. Awakura:Metall. Trans. B, 1985, vol. 16B, pp. 433–39.

    Article  CAS  Google Scholar 

  9. H. Majima and Y. Awakura:Metall. Trans. B, 1988, vol. 19B, pp. 347–54.

    Article  CAS  Google Scholar 

  10. Y. Awakura, S.K. Park, and H. Majima:Metall. Trans. B, 1989, vol. 20B, pp. 763–71.

    Article  CAS  Google Scholar 

  11. V.A. Mikhailov:Russ J. Phys. Chem., 1968, vol. 42, p. 1414.

    Google Scholar 

  12. H. Chen, I. Sangster, T.T. Teng, and F. Lenzi:Can. J. Chem. Eng., 1973, vol. 51, p. 234.

    Article  CAS  Google Scholar 

  13. H. Majima, Y. Awakura, and Y. Kawasaki:Activities of Water and Solutes in the Aqueous Solution System H 2SO4−Mx(SO4)y and HCl−MCl, Agne Shofu Publishing Inc., Tokyo, 1988.

    Google Scholar 

  14. R.A. Robinson and V.E. Bower:J. Res. Natl. Bar. Stand., 1965, vol. 69A, p. 365.

    Google Scholar 

  15. S.K. Park, Y. Awakura, and H. Majima:Metall. Trans. B, 1989, vol. 20B, pp. 13–20.

    Article  CAS  Google Scholar 

  16. S.K. Park, Y. Awakura, and H. Majima:Matall. Trans. B, 1989, vol. 20B, pp. 13–20.

    Article  CAS  Google Scholar 

  17. H. Majima, Y. Awakura, and T. Sato:Denki Kagaku, 1980, vol. 48 (11), pp. 597–602.

    CAS  Google Scholar 

  18. Y. Awakura, T. Michimoto, Y. Takeshima, and H. Majima:Denki Kagaku, 1983, vol. 51 (3), pp. 302–09.

    CAS  Google Scholar 

  19. T. Awakura, S. Mitsuda, and H. Majima:Denki Kagaku, 1982, vol. 50 (6), pp. 494–95.

    CAS  Google Scholar 

  20. Y. Awakura, S. Mitsuda, and H. Majima:Denki Kagaku, 1982, vol. 50 (12), pp. 979–80.

    CAS  Google Scholar 

  21. K.J. Vetter:Electrochemical Kinetics, Academic Press, New York, NY, 1967, p. 46.

    Google Scholar 

  22. H. Majima and Y. Awakura:Metall. Trans. B, 1981, vol. 12B, pp. 141–47.

    Article  CAS  Google Scholar 

  23. R.A. Robinson and R.H. Stokes:Electrolyte Solutions, 2nd ed., Butterworth and Co. Scientific Publications, London, 1959, (a), p. 33, (b) pp. 491–508, (c) pp. 513–15, and (d) pp. 253–61.

    Google Scholar 

  24. Y. Awakura, Y. Takeshima, H. Kondo, and H. Majima:Denki Kagaku, 1984, vol. 52 (2) pp. 90–95.

    CAS  Google Scholar 

  25. H.A.C. McKay and J.K. Perring:Trans. Faraday Soc., 1953, vol. 49, pp. 163–65.

    Article  CAS  Google Scholar 

  26. D. Dobos:Electrochemical Data, Elsevier Scientific Publ. Co., Amsterdam, 1975.

    Google Scholar 

  27. Y. Awakura, A. Uno, and H. Majima:Metall. Trans. B, 1989, vol. 20B, pp. 110–13.

    Article  CAS  Google Scholar 

  28. H. Majima, Y. Awakura, T. Yazaki, and Y. Chikamori:Metall. Trans. B, 1980, vol. 11B, pp. 209–14.

    Article  Google Scholar 

  29. H. Majima, Y. Awakura, and T. Mishima:Metall. Trans. B, 1985, vol. 16B, pp. 23–30.

    Article  CAS  Google Scholar 

  30. Y. Awakura, S. Kamei, and H. Majima:Metall. Trans. B, 1980, vol. 11B, pp. 377–81.

    Article  CAS  Google Scholar 

  31. H. Majima, Y. Awakura, and N. Misaki:Metall. Trans. B, 1981, vol. 12B, pp. 645–49

    Article  CAS  Google Scholar 

  32. H. Majima and Y. Awakura:Extraction Metallurgy '85, IMM, London, 1985, pp. 607–27.

    Google Scholar 

  33. H. Majima, Y. Awakura, and Y. Kawasaki:Metall. Trans. B, 1988, vol. 19B, pp. 505–07.

    Article  CAS  Google Scholar 

  34. K. Tozawa, Y. Umetsu, and T. Ono:Senken-iho, 1981, vol. 37, pp. 89–96.

    CAS  Google Scholar 

  35. K. Tozawa and Y. Umetsu:Conf. Proc. of Hydrometalurgy Research, Development and Plant Practice, K. Osseo-Asare and J.D. Miller, eds. Met. Soc. AIME, Warrendale, PA 1981, pp. 375–89.

    Google Scholar 

  36. H. Majima, E. Peters, Y. Awakura, S.K. Park, and M. Aoki:Metall. Trans. B, 1988, vol. 19B, pp. 53–58.

    Article  CAS  Google Scholar 

  37. T. O'M Bockris and A.K.N. Reddy:Modern Electrochemistry, Plenum Press, New York, NY, 1970, vol. 1, p. 470.

    Google Scholar 

  38. H. Majima, E. Peters, Y. Awakura, and S.K. Park:Metall Trans. B, 1987, vol. 18B, pp. 41–47.

    Article  CAS  Google Scholar 

  39. Y. Awakura, T. Doi, and H. Majima;Metall. Trans. B, 1988, vol. 19B, pp. 5–12.

    Article  CAS  Google Scholar 

  40. Y. Awakura, M. Aoki, A. Tsuchiya, and H. Majima:Metall Trans. B, 1989, vol. 20B, pp. 555–65.

    Article  CAS  Google Scholar 

  41. K.S. Johnson and Pytkowicz: inActivities Coefficients in Electrolyte solutions, Vol. 2, R.M. Pytkowicz, ed., CRC Press, Boca Raton, FL, 1979, pp. 1–62.

    Google Scholar 

  42. Y. Awakura, K. Koyama, Y. Takegawa, and H. Majima:Metall. Trans. B, 1990, vol. 21B, pp. 689–95.

    Article  CAS  Google Scholar 

  43. A.M. Posner:Trans. Faraday Soc., 1953, vol. 49, pp. 389–95.

    Article  CAS  Google Scholar 

  44. T. Yano, T. Sukata, T. Umehara, K. Konishi, and A. Horiuchi:Nippon Kagaku Kaishi, 1974, No. 8, pp. 1373–79.

    Google Scholar 

  45. Y. Awakura, M. Iwai, and H. Majima: inIron Control in Hydrometallurgy, J.E. Dutrizac and A.J. Monhemius, eds., CIM, Toronto, 1986, pp. 202–22.

    Google Scholar 

  46. M. Iwai and H. Majima:Denki Kagaku, 1979, vol. 47, pp. 717–22.

    CAS  Google Scholar 

  47. H. Majima, Y. Awakura, T. Hirato, and T. Tanaka:Can. Metall. Q., 1985, vol. 24, pp. 283–91.

    CAS  Google Scholar 

  48. T. Hirato, M. Kinoshita, Y. Awakura, and H. Majima:Metall. Trnas. B., 1986, vol. 17B, pp. 19–28.

    Article  CAS  Google Scholar 

  49. T. Hirato, H. Majima, and Y. Awakura:Metall Trans. B, 1987, vol. 18B, pp. 31–39.

    Article  CAS  Google Scholar 

  50. T. Hirato, H. Majima, and Y. Awakura:Metall. Trans. B, 1987, vol. 18B, pp. 489–96.

    Article  CAS  Google Scholar 

  51. T. Hirato, H. Hiai, Y. Awakura, and H. Majima:Metall. Trans. B, 1989, vol. 20B, pp. 485–91.

    Article  CAS  Google Scholar 

  52. H. Majima, Y. Awakura, M. Mashima and T. Hirato:Metall. Trans. B, 1988, vol. 19B, pp. 355–63.

    Article  CAS  Google Scholar 

  53. Y. Awakura, T. Hirato, A. Kagawa, Y. Yamada, and H. Majima:Metall. Trans. B, 1991, vol. 22B, pp. 569–74.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Dr. Majima received his Bachelor of Engineering and Doctor of Engineering degrees from Kyoto University. In the past 40 years, he has served as an associate professor at the Research Institute of Mineral Dressing and Metallurgy of Tohoku University, a professor at the Department of Mineral Engineering of the University of British Columbia, and a professor at the Department of Metallurgy of Kyoto University. His research interest is directed toward thermodynamics related to hydrometallurgy. He is the recipient of awards from the Mining and Metallurgical Institute of Japan and the surface Finishing Society of Japan. The Extraction and Processing Lecturer Award honors an outstanding scientific leader in the Field of nonferrous extractive metallurgy with an invitation to present a comprehensive lecture at the TMS Annual Meeting.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Majima, H. Improtance of fundamental study in hydrometallurgy. Metall Mater Trans B 26, 1109–1122 (1995). https://doi.org/10.1007/BF02653995

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02653995

Keywords

Navigation