Abstract
The structure of a new Schiff base, o-tosylaminobenzaldehyde, which has a bulky aliphatic substituent at the azomethine N atom, was determined by X-ray diffraction analysis. The structure contains an intramolecular hydrogen bond N-H...N, flattening the azomethine molecule and closing the six-membered quasiaromatic H-ring.
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References
H. B. Burgi and J. D. Dunitz,Helv. Chim. Acta,53, No. 7, 1747–1764 (1970).
O. S. Filipenko, L. O. Atovmyan, B. L. Tarnopolskii, and Z. S. Safina,Zh. Strukt. Khim.,20, No. 1, 80–88 (1979).
V. I. Ponomarev, O. S. Filipenko, and L. O. Atovmyan,Dokl. Akad. Nauk SSSR,246, No. 2, 321–325 (1979).
A. E. Obodovskaya, Z. A. Starikova, V. K. Trunov, and B. M. Bolotin,Zh. Strukt. Khim.,22, No. 1, 104–108 (1981).
A. E. Obodovskaya, Z. A. Starikova, V. K. Trunov, and B. M. Bolotin, —ibid., 109–113.
S. V. Sereda, M. Yu. Antipin, T. V. Timofeeva, et al.,Ukr. Khim. Zh.,54, No. 8, 855–860 (1988).
M. Calligaris and L. Randaccio, in:Comprehensive Coordination Chemistry, Vol. 2, G. Wilkinson (ed.), Pergamon Press, Oxford (1987), pp. 715–733.
V. S. Sergienko, A. É. Mistryukov, V. V. Litvinov, et al.,Koordinats. Khim.,16, No. 2, 168–176 (1990).
A. D. Garnovskii, A. L. Nivorozhkin, and V. I. Minkin,Coord. Chem. Rev.,126, No. 1/2, 1–69 (1993).
S. B. Bulgarevich, A. A. Polunin, D. Ya. Movshovich, et al.,Zh. Obshch. Khim.,51, No. 10, 2311–2314 (1981).
S. B. Bulgarevich, A. A. Polunin, D. Ya. Movshovich, et al., —ibid.,51, No. 11, 2528–2531 (1981).
S. B. Bulgarevich, D. Ya. Movshovich, T. A. Yusman, et al., —ibid.,60, No. 1/2, 2590–2596 (1990).
N. I. Chernova, Yu. S. Ryabokobylko, V. G. Brudz, and B. M. Bolotin,Zh. Org. Khim.,7, No. 8, 1680–1687 (1971).
B. D. Smith, K. J. Haller, and M. Shang,J. Org. Khim.,58, No. 24, 6950–6957 (1993).
R. Taylor and O. Kennard,J. Am. Chem. Soc.,104, No. 19, 5063–5070 (1982).
G. R. Disiaju,Acc. Chem. Res.,24, No. 10, 290–296 (1991).
K. Oaki, M. Inabe, S. Terani, et al.,Inorg. Chem.,33, 3018–3020 (1994).
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Scientific Research Institute of Physical and Organic Chemistry, Rostov State University. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 3, pp. 544–549, May–June, 1996.
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Burlov, A.S., Mistryukov, A.É., Garnovskii, A.D. et al. Crystal and molecular structure of 2-(n-tosylamino)benzylidene-text-butylimine. J Struct Chem 37, 474–479 (1996). https://doi.org/10.1007/BF02578604
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DOI: https://doi.org/10.1007/BF02578604