Abstract
The compounds [PdCl2L2] and [PdL4] (L=PPh3, AsPh3, SbP3) were studied by thermogra-vimetric and differential thermal analyses in air. The residues of thermal decomposition consist of metallic palladium, except in the case of the complexes containing SbPh3, when the residues are palladium and antimony mixtures in appropriate proportions with respect to the stoichiometry of the related complexes.
Zusammenfassung
Mittels TG und DTA in Luft wurden die Verbindungen [PdCl2L2] und [PdL4] (L=PPh3, AsPh3, SbPh3) untersucht. Die Rückstände der thermischen Zersetzung bestehen aus metallischem Palladium, mit Ausnahme des Falles der Komplexe mit SbPh3, wo die Rückstände Gemische aus Palladium und Antimon in einer der Stöchiometrie der fraglichen Komplexe entsprechenden Menge sind.
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Barbiéri, R.S., Belatto, C.R. & Massabni, A.C. Thermal analyses of coordination compounds. Journal of Thermal Analysis 44, 903–909 (1995). https://doi.org/10.1007/BF02547274
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DOI: https://doi.org/10.1007/BF02547274