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Determination of traces of bismuth by isotopic exchange reaction in the organic phase

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Abstract

A new radioanalytical method has been developed based on homogeneous isotopic exchange in the organic phase. The theory of the method is presented and discussed. This method has been applied for the simple, selective and rapid determination of bismuth based on the isotopic exchange between bismuth diethyldithiocarbamate and bismuth iodide complex labelled with210Bi. As little as 0.01 μg of the metal can be determined.

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References

  1. T. B. Pierce,Analyst, 85 (1960) 166.

    Article  CAS  Google Scholar 

  2. T. B. Handley,Anal. Chem., 36 (1964) 153.

    Article  CAS  Google Scholar 

  3. J. Růžička, J. Starý,Talanta, 14 (1967) 909.

    Article  Google Scholar 

  4. J. Starý, J. Růžička,Talanta, 15 (1968) 505.

    Article  Google Scholar 

  5. J. Starý, The Solvent Extraction of Metal Chelates, Pergamon, Oxford, 1964.

    Google Scholar 

  6. H. Bode,Z. Anal. Chem., 143 (1954) 182.

    Article  CAS  Google Scholar 

  7. H. A. Mottola, E. B. Sandell,Anal. Chim. Acta, 24 (1961) 301.

    Article  CAS  Google Scholar 

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Starý, J., Kratzer, K. & Zeman, A. Determination of traces of bismuth by isotopic exchange reaction in the organic phase. J. Radioanal. Chem. 5, 71–77 (1970). https://doi.org/10.1007/BF02513701

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  • DOI: https://doi.org/10.1007/BF02513701

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