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Sequential Separation and Trace Estimation of Indium(III), Gallium(III), and Thallium(III) in Biological and Standard Samples

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Abstract

A novel method for extracting and measuring trace amounts of indium, gallium, and thallium using a synthesized [2]rotaxane hydroxamic acid is proposed. The method involves extracting the elements at specific pH levels using chloroform and measuring them using spectrophotometry and inductively couples plasma atomic emission spectrometry (ICP-AES). The extraction mechanism and the factors that influence the extraction process are also discussed. The method is shown to be effective for measuring these elements in a variety of samples, such as alloys, environmental samples, minerals, water, and biological samples. The sensitivity of this method is enhanced 60 times by ICP-AES measurements, which makes it useful for trace determination of In, Ga, and Tl.

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Authors and Affiliations

  1. Department of Chemistry, LJ School of Applied Sciences, LJ University, 388210, Ahmedabad, India

    Chandramauly Sharma

  2. Centre of Excellence, LJ University, 388210, Ahmedabad, India

    Yadvendra Agrawal

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  1. Chandramauly Sharma
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  2. Yadvendra Agrawal
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Correspondence to Chandramauly Sharma.

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Sharma, C., Yadvendra Agrawal Sequential Separation and Trace Estimation of Indium(III), Gallium(III), and Thallium(III) in Biological and Standard Samples. J Anal Chem 78, 1525–1536 (2023). https://doi.org/10.1134/S1061934823110084

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  • DOI: https://doi.org/10.1134/S1061934823110084

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