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Synthesis and the fluxional behavior of the 30-electron cationic iron-molybdenum triple-decker complex with a central pentaphospholyl ligand, [(η-C7H7)Mo(μ-η:η-P5)Fe(η-C5Me5)]BF4

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reaction of [(η-C7H7)Mo(MeCN)3)]BF4 with (η-C5Me5)Fe(η-P5) afforded the new 30-electron triple-decker complex [(η-C7H7)Mo(μ-η:η-P5)Fe(η-C5Me5)]BF4. Studies of the temperature dependence of the1H NMR spectra demonstrated that the resulting compound contains a fluxional cyclohepatrienyl ligand.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. R. Kudinov, P. V. Petrovskii & M. I. Rybinskaya

Authors
  1. A. R. Kudinov
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  2. P. V. Petrovskii
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  3. M. I. Rybinskaya
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1374–1376, July, 1999.

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Kudinov, A.R., Petrovskii, P.V. & Rybinskaya, M.I. Synthesis and the fluxional behavior of the 30-electron cationic iron-molybdenum triple-decker complex with a central pentaphospholyl ligand, [(η-C7H7)Mo(μ-η:η-P5)Fe(η-C5Me5)]BF4 . Russ Chem Bull 48, 1362–1364 (1999). https://doi.org/10.1007/BF02495305

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  • DOI: https://doi.org/10.1007/BF02495305

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