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Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

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Abstract

A reaction of the cluster (Et4N)2[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ36) afforded the mononuclear complexes (Et4N)[Mo(Cat36)3] (I) and (Et4N)[MoO(Cat36)2(HCat36)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na2Cat36), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et2O)).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Petrov, M. Yu. Afonin, D. Yu. Naumov & S. N. Konchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Petrov & S. N. Konchenko

  3. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, Russia

    A. V. Piskunov

  4. Lobachevsky State University, Nizhni Novgorod, Russia

    A. V. Piskunov

Authors
  1. P. A. Petrov
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  2. M. Yu. Afonin
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  3. D. Yu. Naumov
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  4. S. N. Konchenko
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  5. A. V. Piskunov
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Correspondence to P. A. Petrov.

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Original Russian Text © P.A. Petrov, M.Yu. Afonin, D.Yu. Naumov, S.N. Konchenko, A.V. Piskunov, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 1, pp. 34–39.

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Petrov, P.A., Afonin, M.Y., Naumov, D.Y. et al. Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand. Russ J Coord Chem 41, 31–36 (2015). https://doi.org/10.1134/S1070328415010078

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  • DOI: https://doi.org/10.1134/S1070328415010078

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